Forster electronic excitation energy transfer upon adsorption of meso-tetra (3-pyridyl) porphyrin on InP@ZnS colloidal quantum dots

被引:11
|
作者
Tovstun, S. A. [1 ]
Martyanova, E. G. [1 ]
Brichkin, S. B. [1 ]
Spirin, M. G. [1 ]
Gak, V. Yu. [1 ]
Kozlov, A. V. [1 ]
Razumov, V. F. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Academician Semenov Ave 1, Chernogolovka 142432, Moscow Region, Russia
基金
俄罗斯科学基金会;
关键词
Colloidal quantum dots; Forster resonance energy transfer; Indium phosphide; Porphyrin; DYE MOLECULES; NANOCRYSTALS; PHOTOLUMINESCENCE; NANOASSEMBLIES; NANOCOMPOSITES; DYNAMICS; LIGAND; LUMINESCENCE; TEMPERATURE; GENERATION;
D O I
10.1016/j.jlumin.2018.04.018
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Adsorption of meso-tetra(3-pyridyl) porphyrin (TPyP) on InP@ZnS colloidal quantum dots (QDs) has been studied by fluorescence spectroscopy. It has been found that after addition of TPyP to a solution of InP@ZnS QDs, the processes of growth of the TPyP photoluminescence intensity and quenching of InP@ZnS QD photoluminescence occur. The kinetics of these processes in the time range from a few seconds to tens of hours is logarithmic, which indicates a dispersion of the activation energy of the dye adsorption. The increase in the photoluminescence intensity of TPyP upon the adsorption is due to Forster resonance energy transfer. The adsorption of TPyP leads to small changes in its spectral characteristics and luminescence lifetime.
引用
收藏
页码:151 / 157
页数:7
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