Study of structure and two-dimension correlation infrared spectroscopy on three rare-earth/3-methylbenzoic acid complexes

被引：28

作者：

Zhao, Lingyan ^{[1
]}

Chen, Yiping ^{[1
]}

Zhang, Hanhui ^{[1
,2
]}

Li, Chaoyu ^{[1
]}

Sun, Ruiqing ^{[1
]}

Yang, Qiyu ^{[1
]}

机构：

[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 920卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

Rare-earth complexes; 3-Methylbenzoic acid; The second ligand; Two-dimensional infrared (2D-IR); LANTHANIDE COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; LUMINESCENCE PROPERTY; TERNARY; SERIES; ARCHITECTURES; CONTRACTION; IONS;

D O I：

10.1016/j.molstruc.2008.12.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three rare-earth complexes with 3-methylbenzoic acid (HL) have been hydrothermally synthesized directly: Yb(C8H7O2)(3) 1 and Ln(C8H7O2)(3)center dot(4,4'-bipy)(0.5) (Ln = Eu 2, Gd 3) (4,4'-bipy = 4.4'-bipyridine). The crystal structures were determined by single crystal X-ray diffraction with the following data: 1: monoclinic, P2(1)/n, a = 13.574(3), b = 8.0438(2), c = 20.652(4) angstrom, beta = 96.14(3)degrees; 2: triclinic, P-1, a = 8.1788(2), b = 12.952 (3), c = 12.968(3) angstrom, alpha = 94.400(3)degrees, beta = 92.260(4), gamma = 101.360(4); the complex 1 is a one-dimensional chain. However. due to the existence of the second ligand-4,4'-bipy, the complexes 2 and 3 are a two-dimensional layer, the Lanthanide contraction makes the difference of the structure between the complexes at the same time. Additionally, in order to explore the structural characteristic, the 2D-IR correlation spectroscopy containing the temperature-induced structural variations and magnetism-induced structural variations is used. Photo-luminescent properties of 1 and 2 are discussed in detail. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：441 / 449

页数：9

共 37 条

[1] Structural variations across the lanthanide series of macrocyclic DOTA complexes: Insights into the design of contrast agents for magnetic resonance imaging [J].

Benetollo, F ;

Bombieri, G ;

Calabi, L ;

Aime, S ;

Botta, M .

INORGANIC CHEMISTRY, 2003, 42 (01) :148-157

[2]

BETTENCOURTDIAS AD, 2006, CHEM SOC DALTON T, P4093

[3] Structural studies of the whole series of lanthanide double-decker compounds with mixed 2,3-naphthalocyaninato and octaethylporphyrinato ligands [J].

Bian, YZ ;

Wang, DQ ;

Wang, RM ;

Weng, LH ;

Dou, JM ;

Zhao, DY ;

Ng, DKP ;

Jiang, JZ .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (05) :844-849

[4] Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[5] The influence of the chelate effect on supramolecular structure formation: synthesis and crystal structures of zinc thiourea and and thiosemicarbazide complexes with terephthalate [J].

Burrows, AD ;

Menzer, S ;

Mingos, DMP ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4237-4240

[6] Structural variations in rare earth benzoate complexes - Part I. Lanthanum [J].

Busskamp, Hendrik ;

Deacon, Glen B. ;

Hilder, Matthias ;

Junk, Peter C. ;

Kynast, Ulrich H. ;

Lee, Winnie W. ;

Turner, David R. .

CRYSTENGCOMM, 2007, 9 (05) :394-411

[7] Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Sun, DF ;

Liang, YC ;

Hong, MC ;

Tatsumi, K ;

Shi, Q .

INORGANIC CHEMISTRY, 2002, 41 (08) :2087-2094

[8] The structure and two-dimensional correlation infrared spectroscopy study of a new 2D polyoxomolybdate complex containing β-octamolybdate linked up by potassium ions:: (4,4′-Hbpy)2(K2Mo8O26) [J].

Chen, YP ;

Shen, XM ;

Zhang, HH ;

Huang, CC ;

Cao, YN ;

Sun, RQ .

VIBRATIONAL SPECTROSCOPY, 2006, 40 (01) :142-147

[9] Synthesis, crystal structure and characterization of ternary complexes of lanthanide(III) 3,5-di-tert-butyl-γ-resorcylate with substituted pyridine-N-oxide [J].

Chu, Y ;

Gao, YC ;

Shen, FJ ;

Liu, X ;

Wang, YY ;

Shi, QZ .

POLYHEDRON, 1999, 18 (27) :3723-3727

[10] Synthesis of complexes of 2,2′:6′,2"-terpyridine and 1,10-phenanthroline with lanthanide thiocyanates;: the molecular structures of [Ln(terpy)2(NCS)3] (Ln = Pr, Nd), [Nd(terpy)2(NCS)3]•2EtOH and [Ln(phen)3(NCS)3]•EtOH (Ln = Pr, Nd) [J].

Cotton, SA ;

Franckevicius, V ;

How, RE ;

Ahrens, B ;

Ooi, LL ;

Mahon, MF ;

Raithby, PR ;

Teat, SJ .

POLYHEDRON, 2003, 22 (11) :1489-1497

← 1 2 3 4 →