Baylis-Hillman reaction in [bdmim][[PF6] ionic liquid

被引:97
作者
Hsu, JC [1 ]
Yen, YH [1 ]
Chu, YH [1 ]
机构
[1] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan
关键词
Baylis-Hillman reaction; ionic liquid;
D O I
10.1016/j.tetlet.2004.04.099
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new use of ionic liquid [bdmim][PF6] as solvent for the Baylis-Hillman reaction is presented. Unlike the commonly used [bmim][PF6] that evidently reacts with electrophilic aldehydes under basic conditions, ionic liquid [bdmim][PF6] is inert and the Baylis-Hillman reaction in [bdmim][PF6] proceeds smoothly with better yield. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4673 / 4676
页数:4
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