Influence of different templates on the textured Bi0.5(Na1-xKx)0.5TiO3 piezoelectric ceramics by the reactive templated grain growth process

One-dimensional TiO2 whiskers were used first time as templates to fabricate grain-oriented Bi-0.5(Na1-xKx)(0.5)TiO3 (x = 0.15) (BNKT) piezoelectric ceramics with the reactive templated grain growth process. The influences of sintering temperature and the template concentration on the orientation of BNKT were investigated. The orientation factor along (h 0 0) direction was only 26.41% since the fibrous TiO2 particles on the surface were aligned along the extrusion direction while many randomly oriented particles were in the middle of the rods. The reaction and crystal formation of BNKT ceramic from fibrous TiO2 templates is a dissolution-recrystallization process on its surface and the dissolution of fibrous TiO2 templates is detrimental to the grain orientation. The orientation factor of more than 70% was obtained successfully when the plate-like Bi4Ti3O12 was used as the templates using a tape casting process. The reaction and crystallization of the two kinds of templates in the whole sintering process were discussed and the grain orientation mechanism was also elucidated in this paper. (C) 2004 Elsevier Ltd and Techna Group S.r.l. All rights reserved.