A reversible transformation of functional groups in graphene oxide with loading and unloading of metal compounds

被引:14
作者
Zhang, Xiaoting [1 ]
Zhou, Jisheng [1 ]
Song, Huaihe [1 ]
Liu, Chengcheng [1 ]
Zhang, Su [1 ]
Chen, Xiaohong [1 ]
机构
[1] Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
LITHIUM-ION BATTERIES; ACID MONOLAYERS; GRAPHITE OXIDE; NANOSHEETS; REDUCTION; STORAGE; PERFORMANCE; MOLECULES; COVALENT; PLATFORM;
D O I
10.1016/j.carbon.2015.12.040
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Functional groups (FGs) in graphene oxide (GO) play an important role in the properties and applications of GO and its related materials. However, there are limited studies about the reversible transformation of FGs in response to external stimuli. In this paper, we report an experimental investigation on the response of FGs to the stimuli of transitional metal compounds. Reversible transformation of FGs on GO with loading and unloading of metal compounds was found. This interesting phenomenon could be helpful to not only enrich the reactivity of FGs in GO, but also provide new insights for designing advanced graphene-based nanomaterials. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:370 / 374
页数:5
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