Structural variability in neptunium(V) oxalate compounds:: Synthesis and structural characterization of Na2NpO2(C2O4)OH•H2O

被引：19
作者：
Bean, AC
Garcia, E
Scott, BL
Runde, W
机构：
[1] Los Alamos Natl Lab, Nucl Mat Div, Los Alamos, NM 87545 USA
[2] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA
来源：
INORGANIC CHEMISTRY | 2004年 / 43卷 / 20期
关键词：
D O I：
10.1021/ic0492082
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of a Np-237(V) stock solution in the presence of oxalic acid, calcium chloride, and sodium hydroxide under hydrothermal conditions produces single crystals of a neptunium(V) oxalate, Na2NpO2(C2O4)(OHH2O)-H-.. The structure consists of one-dimensional chains running down the a axis and is the first example of a neptunium(V) oxalate compound containing hydroxide anions.
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页码：6145 / 6147
页数：3
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