Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides

被引：72

作者：

Leca, D ^{[1
]}

Toussaint, A ^{[1
]}

Mareau, C ^{[1
]}

Fensterbank, L ^{[1
]}

Lacôte, E ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, Chim Organ Lab, UMR 7611, CNRS, F-75005 Paris, France

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 20期

关键词：

D O I：

10.1021/ol0485520

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulfonimidamides lead efficiently to nitrenes and have been converted to sulfimides, sulfoximines, and aziridines in good yields, through a copper-mediated multicomponent reaction. The stereogenic sulfur atom and the trivalent nitrogen atom present in the molecules open the way to asymmetric synthesis, whose first results are presented.

引用

页码：3573 / 3575

页数：3

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