Square Tetrapalladium Sheet Sandwich Complexes: Cyclononatetraenyl as a Versatile Face-Capping Ligand

被引：75

作者：

Murahashi, Tetsuro ^{[1
]}

Inoue, Ryou

Usui, Kentaro

Ogoshi, Sensuke

机构：

[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 29期

关键词：

PALLADIUM; DERIVATIVES; CLUSTER; CYCLOOCTATETRAENYL; REACTIVITY; SYSTEM; ANION;

D O I：

10.1021/ja903679f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unusual square tetrapalladium sheet sandwich complex, [Pd(4)(mu(4)-C(9)H(9)) (mu(4)-C(8)H(8))][B(Ar(f))(4)] has been isolated and structurally characterized. X-ray structure analysis showed that the square palladium sheet is flanked by the nine-membered cyclononatetraenyl and eight-membered cyclooctatetraene ligands to form a square metal sheet molecular sandwich structure. The coordinative unsaturation of the complex was revealed by phosphine titration experiments.

引用

页码：9888 / +

页数：3

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