Synthesis and structural characterization of the complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine

被引：5

作者：

Tian, LJ ^{[1
]}

Zhou, ZY ^{[1
]}

Zhao, B ^{[1
]}

Sun, HT ^{[1
]}

Yu, WT ^{[1
]}

Yang, P ^{[1
]}

机构：

[1] Qufu Normal Univ, Dept Chem, Qufu 273165, Shangdong, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2000年 / 30卷 / 02期

关键词：

D O I：

10.1080/00945710009351764

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide (HMPA) and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine (H2L) have been synthesized and characterized by means of elemental analyses, IR and H-1 NMR spectra and an X-ray single crystal diffraction study. The spectral data indicate that these complexes are all six-coordinate tin compounds. The crystal structure of MeOCO-CH(CH3)CH2SnCl3. HMPA shows that the tin atom adopts a distorted octahedral geometry via the oxygen atoms of HMPA and intramolecular carbonyl group.

引用

页码：307 / 317

页数：11

共 24 条

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