A novel heterobimetallic W-Ge compound.: X-ray crystal structure of [W(μ-Cl)(GeCl3)(CO)3(η4-C7H8)]

被引：7

作者：

Szymanska-Buzar, T ^{[1
]}

Glowiak, T ^{[1
]}

Czelusniak, I ^{[1
]}

Górski, M ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 09期

关键词：

tungsten; germanium; crystal structure; heterobimetallic compound; alkene complex;

D O I：

10.1016/S1387-7003(02)00525-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new heterobimetallic complex [W(mu-Cl)(GeCl3)(CO)(3)(eta(4)-C7H8)] (1) has been prepared by photochemical reaction of W(CO)(6) with bicyclo[2.2.1]hepta-2,5-diene (NBD) and GeCl4. The structure of compound I was established by X-ray crystallography. The IR, H-1 and C-13 NMR spectra are also described and correlated with the crystallographically observed geometry. Compound 1 is noteworthy since it is the first alkene complex of tungsten isolated in W(CO)(6) - Lewis acid photocatalytic system. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：682 / 684

页数：3

共 25 条

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