Effect of Different Alcohols and Palm and Palm Kernel (Palmist) Oils on Biofuel Properties for Special Uses

被引：20

作者：

Cardoso Bejan, Claudia Cristina ^{[1
]}

Celante, Vinicius Guilherme ^{[2
]}

Ribeiro de Castro, Eustaquio Vinicius ^{[3
]}

Duarte Pasa, Vanya Marcia ^{[4
]}

机构：

[1] Univ Fed Rural Pernambuco, Dept Quim, BR-52171900 Recife, PE, Brazil

[2] Inst Fed Educ Ciencia & Tecnol Espirito Santo, BR-29192733 Aracruz, ES, Brazil

[3] Univ Fed Espirito Santo, Dept Quim, BR-29060900 Vitoria, ES, Brazil

[4] Univ Fed Minas Gerais, Inst Ciencias Exatas ICEx, Dept Quim, Fuel Lab, BR-31270901 Belo Horizonte, MG, Brazil

来源：

ENERGY & FUELS | 2014年 / 28卷 / 08期

关键词：

CRYSTALLIZATION TEMPERATURE; PHYSICAL-PROPERTIES; CHEMICAL-STRUCTURE; BIODIESEL FUEL; VEGETABLE-OIL; TRANSESTERIFICATION; ETHANOL; OPTIMIZATION; ESTERS; ACID;

D O I：

10.1021/ef500776u

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The properties of biodiesel are determined by its oleaginous composition and the alcohol used in the transesterification. This study was performed using palm and palmist oils and methyl, ethyl, isopropyl, and benzyl alcohols to investigate their influence on the cold flow properties, density, and viscosity of the resulting biofuel. The products were also characterized by H-1 nuclear magnetic resonance (NMR) and high-performance liquid chromatography (HPLC) analyses. Biofuel produced from palmist oil had different properties compared to biofuel synthesized from palm oil because of its lower average chain length and lower content of unsaturation. Biodiesel produced with palmist oil and isopropyl alcohol had the lowest values of cold filter plugging point (CFPP) (-16 degrees C) and density (860 kg/m(3)). The use of benzyl alcohol yielded a biofuel with high viscosity and density values that do not adhere to any international specifications for biodiesel.

引用

页码：5128 / 5135

页数：8

共 31 条

[21] Reducing the crystallization temperature of biodiesel by winterizing methyl soyate [J].

Lee, I ;

Johnson, LA ;

Hammond, EG .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1996, 73 (05) :631-636

[22] USE OF BRANCHED-CHAIN ESTERS TO REDUCE THE CRYSTALLIZATION TEMPERATURE OF BIODIESEL [J].

LEE, I ;

JOHNSON, LA ;

HAMMOND, EG .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (10) :1155-1160

[23] A review on palm oil biodiesel as a source of renewable fuel [J].

Mekhilef, S. ;

Siga, S. ;

Saidur, R. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (04) :1937-1949

[24] Optimization of biodiesel production from palm oil under supercritical ethanol conditions using hexane as co-solvent: A response surface methodology approach [J].

Muppaneni, Tapaswy ;

Reddy, Harvind K. ;

Ponnusamy, Sundaravadivelnathan ;

Patil, Prafulla D. ;

Sun, Yingqiang ;

Dailey, Peter ;

Deng, Shuguang .

FUEL, 2013, 107 :633-640

[25] Production of Bio-Diesel from Palm Kernel Oil and Groundnut Oil [J].

Ojolo, S. J. ;

Adelaja, A. O. ;

Sobamowo, G. M. .

ADVANCES IN MATERIALS AND SYSTEMS TECHNOLOGIES III, 2012, 367 :501-506

[26] Winterization of peanut biodiesel to improve the cold flow properties [J].

Perez, Angel ;

Casas, Abraham ;

Maria Fernandez, Carmen ;

Jesus Ramos, Maria ;

Rodriguez, Lourdes .

BIORESOURCE TECHNOLOGY, 2010, 101 (19) :7375-7381

[27] Correlation between the chemical structure of biodiesel and its physical properties [J].

Refaat, A. A. .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2009, 6 (04) :677-694

[28] Correlating chemical structure and physical properties of vegetable oil esters [J].

Rodrigues, Jorge de A., Jr. ;

Cardoso, Fabianne de P. ;

Lachter, Elizabeth R. ;

Estevao, Luciana R. M. ;

Lima, Edson ;

Nascimento, Regina S. V. .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2006, 83 (04) :353-357

[29] An experimental comparison of transesterification process with different alcohols using acid catalysts [J].

Saravanan, N. ;

Puhan, Sukumar ;

Nagarajan, G. ;

Vedaraman, N. .

BIOMASS & BIOENERGY, 2010, 34 (07) :999-1005

[30] Physical and chemical properties of ethanol-diesel fuel blends [J].

Torres-Jimenez, Eloisa ;

Jerman, Marta Svoljsak ;

Gregorc, Andreja ;

Lisec, Irenca ;

Dorado, M. Pilar ;

Kegl, Breda .

FUEL, 2011, 90 (02) :795-802

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