Alkaline polymer electrolyte fuel cells stably working at 80 °C

被引:297
作者
Peng, Hanging [1 ]
Li, Qihao [1 ]
Hu, Meixue [1 ]
Xiao, Li [1 ]
Lu, Juntao [1 ]
Zhuang, Lin [1 ,2 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China
基金
中国国家自然科学基金;
关键词
OXYGEN-REDUCTION; STABILITY; CATIONS; POLYAROMATICS; DEGRADATION; MEMBRANES;
D O I
10.1016/j.jpowsour.2018.04.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alkaline polymer electrolyte fuel cells are a new class of polymer electrolyte fuel cells that fundamentally enables the use of nonprecious metal catalysts. The cell performance mostly relies on the quality of alkaline polymer electrolytes, including the ionic conductivity and the chemical/mechanical stability. For a long time, alkaline polymer electrolytes are thought to be too weak in stability to allow the fuel cell to be operated at elevated temperatures, e.g., above 60 degrees C. In the present work, we report a progress in the state-of-the-art alkaline polymer electrolyte fuel cell technology. By using a newly developed alkaline polymer electrolyte, quaternary ammonia poly (N-methyl-piperidine-co-p-terphenyl), which simultaneously possesses high ionic conductivity and excellent chemical/mechanical stability, the fuel cell can now be stably operated at 80 degrees C with high power density. The peak power density reaches ca. 1.5 W/cm(2) at 80 degrees C with PVC catalysts used in both the anode and the cathode. The cell works stably in a period of study over 100 h.
引用
收藏
页码:165 / 167
页数:3
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