Ultrafast transient absorption spectroscopy of the hydrated electron: A theory

被引：37

作者：

Bratos, S

Leicknam, JC

机构：

[1] Lab. de Phys. Theorique des Liquides, Univ. Pierre et Marie Curie, 75252 Paris Cedex 05, Case Courrier 121

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 261卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)00930-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theory is proposed to study ultrafast transient absorption of the hydrated electron. This theory is a statistical theory using a correlation function description of the nonlinear optical processes involved. Time- and frequency-resolved spectra are examined for both coherent and incoherent incident fields. The nonmonotonic behavior of spectral transients is studied in detail.

引用

页码：117 / 122

页数：6

共 18 条

[1] ULTRAFAST TRANSIENT-ABSORPTION SPECTROSCOPY OF THE AQUEOUS SOLVATED ELECTRON [J].

ALFANO, JC ;

WALHOUT, PK ;

KIMURA, Y ;

BARBARA, PF .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5996-5998

[2] EXCITED-STATES OF A HYDRATED ELECTRON AND AQUEOUS CHLORIDE BY COMPUTER-SIMULATION [J].

BORGIS, D ;

STAIB, A .

CHEMICAL PHYSICS LETTERS, 1994, 230 (4-5) :405-413

[3] ULTRAFAST INFRARED PUMP-PROBE SPECTROSCOPY OF WATER - A THEORETICAL DESCRIPTION [J].

BRATOS, S ;

LEICKNAM, JC .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (06) :4536-4546

[4] TEMPERATURE AND ISOTOPE EFFECTS ON THE SHAPE OF THE OPTICAL-ABSORPTION SPECTRUM OF SOLVATED ELECTRONS IN WATER [J].

JOU, FY ;

FREEMAN, GR .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (18) :2383-2387

[5] ULTRAFAST TRANSIENT ABSORPTION-SPECTROSCOPY OF THE SOLVATED ELECTRON IN WATER [J].

KIMURA, Y ;

ALFANO, JC ;

WALHOUT, PK ;

BARBARA, PF .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (13) :3450-3458

[6] PHOTODISSOCIATION AND VIBRATIONAL-RELAXATION OF I-2(-) IN ETHANOL [J].

KLINER, DAV ;

ALFANO, JC ;

BARBARA, PF .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5375-5389

[7] FEMTOSECOND STUDIES OF THE PRESOLVATED ELECTRON - AN EXCITED-STATE OF THE SOLVATED ELECTRON [J].

LONG, FH ;

LU, H ;

EISENTHAL, KB .

PHYSICAL REVIEW LETTERS, 1990, 64 (12) :1469-1472

[8] HOLE-BURNING SPECTROSCOPY OF POLAR-MOLECULES IN POLAR-SOLVENTS - SOLVATION DYNAMICS AND VIBRATIONAL-RELAXATION [J].

LORING, RF ;

YAN, YJ ;

MUKAMEL, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (06) :1302-1305

[9] COMPUTER-SIMULATION OF THE DYNAMICS OF AQUEOUS SOLVATION [J].

MARONCELLI, M ;

FLEMING, GR .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (08) :5044-5069

[10] EXCESS ELECTRONS IN LIQUID WATER - 1ST EVIDENCE OF A PREHYDRATED STATE WITH FEMTOSECOND LIFETIME [J].

MIGUS, A ;

GAUDUEL, Y ;

MARTIN, JL ;

ANTONETTI, A .

PHYSICAL REVIEW LETTERS, 1987, 58 (15) :1559-1562

← 1 2 →