Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins

被引：33
|
作者：
Yu, Mengmeng [1 ]
Jing, Huize [1 ]
Liu, Xu [1 ]
Fu, Xuefeng [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
来源：
ORGANOMETALLICS | 2015年 / 34卷 / 24期
关键词：
SI-H BOND; ORGANOMETALLIC REACTIONS; SUBSTRATE REACTIONS; FACILE SYNTHESIS; RH-OH; OXIDATION; COMPLEXES; ACTIVATION; REACTIVITY; ORGANOSILANES;
D O I：
10.1021/acs.organomet.5b00521
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)Rh-I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)Rh-H was observed as the key intermediate through stoichiometric activation of the Si-H bond by (TAP)Rh-I. Addition of water drove the stoichiometric activation of Si-H into catalysis.
引用
收藏
页码：5754 / 5758
页数：5
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