Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins

被引：33

作者：

Yu, Mengmeng ^{[1
]}

Jing, Huize ^{[1
]}

Liu, Xu ^{[1
]}

Fu, Xuefeng ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 24期

关键词：

SI-H BOND; ORGANOMETALLIC REACTIONS; SUBSTRATE REACTIONS; FACILE SYNTHESIS; RH-OH; OXIDATION; COMPLEXES; ACTIVATION; REACTIVITY; ORGANOSILANES;

D O I：

10.1021/acs.organomet.5b00521

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)Rh-I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)Rh-H was observed as the key intermediate through stoichiometric activation of the Si-H bond by (TAP)Rh-I. Addition of water drove the stoichiometric activation of Si-H into catalysis.

引用

页码：5754 / 5758

页数：5

共 37 条

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CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (10) : 3314 - 3326
[2] Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)2]2
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[4] Catalytic Hydrogen Generation from the Hydrolysis of Silanes by Ruthenium Complexes
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[8] Visible-Light-Promoted Manganese-Catalyzed Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides
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[9] Visible-Light-Promoted Mn-Catalyzed C(sp3)-H Amidation with Dioxazolones
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[10] Photochemical generation of manganese(IV)-oxo porphyrins by visible light photolysis of dimanganese(III) μ-oxo bis-porphyrins
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