Preparation and Characterization of Hybrid Ozone Resistance Coating Film Using Carbon Nanotube

被引：2
|
作者：
Kim, Sung Rae [1 ,2 ]
Lee, Sang Goo [3 ]
Yang, Jeong Min [1 ]
Lee, Jong Dae [1 ]
机构：
[1] Chungbuk Natl Univ, Dept Chem Engn, Cheongju 361763, Chungbuk, South Korea
[2] Korea Conform Labs, Chungbuk 363883, South Korea
[3] Korea Res Inst Chem Technol, Div Green Chem, Taejon 305343, South Korea
来源：
POLYMER-KOREA | 2014年 / 38卷 / 05期
关键词：
carbon nanotube; 2,2,2-trifluoroethylmethacrylate; ozone resistance; sol-gel; UV-curable; hybrid coating;
D O I：
10.7317/pk.2014.38.5.573
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.
引用
收藏
页码：573 / 579
页数：7
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