Surface modification of TiO2 by adding V2O5 nanocatalytic system for hydrogen generation

被引:17
作者
Gnanasekaran, Lalitha [1 ]
Rajendran, Saravanan [1 ]
Karimi-Maleh, Hassan [2 ]
Priya, A. K. [3 ]
Qin, Jiaqian [4 ]
Soto-Moscoso, Matias [5 ]
Ansar, Sabah [6 ]
Bathula, Chinna [7 ]
机构
[1] Univ Tarapaca, Fac Ingn, Dept Ingn Mecan, Avda Gen Velasquez, Arica 1775, Chile
[2] Univ Elect Sci & Technol China UESTC, Sch Resources & Environm, Chengdu 611731, Peoples R China
[3] KPR Inst Engn & Technol, Dept Civil Engn, Coimbatore 641407, Tamil Nadu, India
[4] Chulalongkorn Univ, Met & Mat Sci Res Inst, Bangkok 10330, Thailand
[5] Univ Autonoma Chile, Santiago, Chile
[6] King Saud Univ, Coll Appl Med Sci, Dept Clin Lab Sci, POB 10219, Riyadh 11433, Saudi Arabia
[7] Dongguk Univ Seoul, Div Elect & Elect Engn, Seoul 04620, South Korea
关键词
Surface modification; Titanium-di-oxide; Vanadium pentoxide; Visible light; Hydrogen production; ELECTROCHEMICAL PROPERTIES; TIO2-V2O5; NANOCOMPOSITES; PHOTOCATALYTIC ACTIVITY; DEGRADATION; PERFORMANCE; WATER;
D O I
10.1016/j.cherd.2022.03.046
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The surface modification of titanium-di-oxide semiconductor was done by adding V2O5 for enhanced visible light activity for generation of hydrogen. Hence, the main goal of the present work is to achieve the visible light activity using the synthesized photocatalyst for hydrogen production through water splitting. Hydrogen exists in nature and benefits the ecosystem by reducing the carbon emissions in the environment. Therefore, it is a self motivated choice of researchers to produce hydrogen in large scale to save the environment from severe pollution hazards. Meanwhile, photocatalytic activity proves to be the excellent source for hydrogen generation. In this connection, the nanocomposite TiO2-V2O5 was synthesized by blending both sol-gel and thermal decomposition methods. The structural and morphological properties, surface area determination, absorption and band gap studies were carried out via various sophisticated instruments. The TiO2-V2O5 composite system exhibits lower band gap that favored the photocatalytic activity in promoting hydrogen production. (c) 2022 Institution of Chemical Engineers. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:114 / 119
页数:6
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