Synthesis and mesomorphic properties of new imines and copper(II) complexes

被引：12
作者：
Bilgin-Eran, B [1 ]
Yörür, Ç [1 ]
Uzman, S [1 ]
机构：
[1] Yildiz Teknik Univ, Dept Chem, TR-34210 Istanbul, Turkey
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 655卷 / 1-2期
关键词：
liquid crystals; metallomesogens; Schiff bases; copper(II) complexes;
D O I：
10.1016/S0022-328X(02)01425-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and mesomorphic properties of a serie of 4-(alkyloxy)-N-(4-hexylphenyl)-2-hydroxybenzalimine (2) and their copper(H) complexes (3) are reported. The compounds were characterized by spectroscopic methods (1R, H-1-, C-13-NMR and MS). The calamitic liquid crystal series of imines (2) and copper(II) complexes (3) exhibited smectic mesophases, which were characterized by differential scanning calorimetry (DSC) analysis and optical polarizing microscopy. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码：105 / 110
页数：6
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