A simple route to preparing γ-Fe2O3/RGO composite electrode materials for lithium ion batteries

被引:110
作者
Xu, Binghui [1 ,2 ]
Guan, Xianggang [1 ]
Zhang, Lian Ying [1 ]
Liu, Xiaowei [1 ]
Jiao, Zhengbo [1 ]
Liu, Xuehua [1 ]
Hu, Xiaoqi [2 ]
Zhao, X. S. [1 ,3 ]
机构
[1] Qingdao Univ, Inst Mat Energy & Environm, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Coll Mat Sci & Engn, Qingdao 266071, Peoples R China
[3] Univ Queensland, Sch Chem Engn, Brisbane, Qld 4072, Australia
基金
中国博士后科学基金; 澳大利亚研究理事会;
关键词
PERFORMANCE ANODE MATERIAL; 3-DIMENSIONAL GRAPHENE; ENERGY-STORAGE; FE2O3; NANOSHEETS; OXIDE; NANOFIBERS; CARBON;
D O I
10.1039/c7ta10052c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple approach to synthesizing -Fe2O3 nanoparticles encapsulated by reduced graphene oxide (RGO) sheets is demonstrated for the first time. It was found that iron metal can substantially reduce few-layer graphene oxide (GO) to form reduced graphene oxide (RGO) in GO aqueous suspension under ambient conditions, and in the meantime be oxidized to form -Fe2O3 nanoparticles dispersed on the surface of RGO sheets. The -Fe2O3/RGO composite delivered both stable cycling performance and good rate capability when used as an anode in a lithium-ion battery cell. This novel experimental method for synthesizing -Fe2O3/RGO composite materials is cost-effective, eco-friendly and suitable for synthesizing other metal oxide/RGO composite materials.
引用
收藏
页码:4048 / 4054
页数:7
相关论文
共 32 条
[21]   Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review [J].
Su, Xin ;
Wu, Qingliu ;
Li, Juchuan ;
Xiao, Xingcheng ;
Lott, Amber ;
Lu, Wenquan ;
Sheldon, Brian W. ;
Wu, Ji .
ADVANCED ENERGY MATERIALS, 2014, 4 (01)
[22]   Hierarchical Dendrite-Like Magnetic Materials of Fe3O4, γ-Fe2O3, and Fe with High Performance of Microwave Absorption [J].
Sun, Genban ;
Dong, Bingxiang ;
Cao, Minhua ;
Wei, Bingqing ;
Hu, Changwen .
CHEMISTRY OF MATERIALS, 2011, 23 (06) :1587-1593
[23]   Solvothermal Synthesized γ-Fe2O3/graphite Composite for Supercapacitor [J].
Wang, Miao ;
Cheng, Suzhen ;
Dang, Guoju ;
Min, Fanqi ;
Li, Haiyan ;
Zhang, Quansheng ;
Xie, Jingying .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (07) :6292-6303
[24]   Three-Dimensional Graphene-Based Macro- and Mesoporous Frameworks for High-Performance Electrochemical Capacitive Energy Storage [J].
Wu, Zhong-Shuai ;
Sun, Yi ;
Tan, Yuan-Zhi ;
Yang, Shubin ;
Feng, Xinliang ;
Muellen, Klaus .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (48) :19532-19535
[25]   Direct self-assembly of Fe2O3/reduced graphene oxide nanocomposite for high-performance lithium-ion batteries [J].
Xiao, Lisong ;
Schroeder, Matthias ;
Kluge, Sebastian ;
Balducci, Andrea ;
Hagemann, Ulrich ;
Schulzad, Christof ;
Wiggers, Hartmut .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (21) :11566-11574
[26]   Graphene-based electrodes for electrochemical energy storage [J].
Xu, Chaohe ;
Xu, Binghui ;
Gu, Yi ;
Xiong, Zhigang ;
Sun, Jing ;
Zhao, X. S. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1388-1414
[27]   Encapsulating iron oxide@carbon in carbon nanofibers as stable electric conductive network for lithium-ion batteries [J].
Xu, Xiaoqian ;
Wan, Yuanxin ;
Liu, Jingwen ;
Chen, Yaojun ;
Li, Linling ;
Wang, Xiaoliang ;
Xue, Gi ;
Zhou, Dongshan .
ELECTROCHIMICA ACTA, 2017, 246 :766-775
[28]   Sandwiched graphene inserted with graphene-encapsulated yolk-shell γ-Fe2O3 nanoparticles for efficient lithium ion storage [J].
Zhang, Miao ;
Liu, Enzuo ;
Cao, Tingting ;
Wang, Huayu ;
Shi, Chunsheng ;
Li, Jiajun ;
He, Chunnian ;
He, Fang ;
Ma, Liying ;
Zhao, Naiqin .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (15) :7035-7042
[29]   Rational construction the composite of graphene and hierarchical structure assembled by Fe2O3 nanosheets for lithium storage [J].
Zhao, Yongjie ;
Zhai, Ximei ;
Yan, Dong ;
Ding, Caihua ;
Wu, Nan ;
Su, Dezhi ;
Zhao, Yuzhen ;
Zhou, Heping ;
Zhao, Xiuchen ;
Li, Jingbo ;
Jin, Haibo .
ELECTROCHIMICA ACTA, 2017, 243 :18-25
[30]   Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries [J].
Zhu, Xianjun ;
Zhu, Yanwu ;
Murali, Shanthi ;
Stollers, Meryl D. ;
Ruoff, Rodney S. .
ACS NANO, 2011, 5 (04) :3333-3338