A simple route to preparing γ-Fe2O3/RGO composite electrode materials for lithium ion batteries

被引:110
作者
Xu, Binghui [1 ,2 ]
Guan, Xianggang [1 ]
Zhang, Lian Ying [1 ]
Liu, Xiaowei [1 ]
Jiao, Zhengbo [1 ]
Liu, Xuehua [1 ]
Hu, Xiaoqi [2 ]
Zhao, X. S. [1 ,3 ]
机构
[1] Qingdao Univ, Inst Mat Energy & Environm, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Coll Mat Sci & Engn, Qingdao 266071, Peoples R China
[3] Univ Queensland, Sch Chem Engn, Brisbane, Qld 4072, Australia
基金
中国博士后科学基金; 澳大利亚研究理事会;
关键词
PERFORMANCE ANODE MATERIAL; 3-DIMENSIONAL GRAPHENE; ENERGY-STORAGE; FE2O3; NANOSHEETS; OXIDE; NANOFIBERS; CARBON;
D O I
10.1039/c7ta10052c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple approach to synthesizing -Fe2O3 nanoparticles encapsulated by reduced graphene oxide (RGO) sheets is demonstrated for the first time. It was found that iron metal can substantially reduce few-layer graphene oxide (GO) to form reduced graphene oxide (RGO) in GO aqueous suspension under ambient conditions, and in the meantime be oxidized to form -Fe2O3 nanoparticles dispersed on the surface of RGO sheets. The -Fe2O3/RGO composite delivered both stable cycling performance and good rate capability when used as an anode in a lithium-ion battery cell. This novel experimental method for synthesizing -Fe2O3/RGO composite materials is cost-effective, eco-friendly and suitable for synthesizing other metal oxide/RGO composite materials.
引用
收藏
页码:4048 / 4054
页数:7
相关论文
共 32 条
[1]   Biomimetic Spider-Web-Like Composites for Enhanced Rate Capability and Cycle Life of Lithium Ion Battery Anodes [J].
Bhattacharya, Pallab ;
Kota, Manikantan ;
Suh, Dong Hoon ;
Roh, Kwang Chul ;
Park, Ho Seok .
ADVANCED ENERGY MATERIALS, 2017, 7 (17)
[2]   An overview of graphene in energy production and storage applications [J].
Brownson, Dale A. C. ;
Kampouris, Dimitrios K. ;
Banks, Craig E. .
JOURNAL OF POWER SOURCES, 2011, 196 (11) :4873-4885
[3]   Three-dimensional carbon-coated Si/rGO nanostructures anchored by nickel foam with carbon nanotubes for Li-ion battery applications [J].
Chang, Jingbo ;
Huang, Xingkang ;
Zhou, Guihua ;
Cui, Shumao ;
Mao, Shun ;
Chen, Junhong .
NANO ENERGY, 2015, 15 :679-687
[4]   Graphene-based materials in electrochemistry [J].
Chen, Da ;
Tang, Longhua ;
Li, Jinghong .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3157-3180
[5]   Enhanced rate capability of a lithium ion battery anode based on liquid-solid-solution assembly of Fe2O3 on crumpled graphene [J].
Cui, Xinghong ;
Zhu, Yanfang ;
Li, Fei ;
Liu, Daijun ;
Chen, Jianjun ;
Zhang, Yuxin ;
Zhang, Li Li ;
Ji, Junyi .
RSC ADVANCES, 2016, 6 (11) :9007-9012
[6]   Facile Synthesis of Graphene Nanosheets via Fe Reduction of Exfoliated Graphite Oxide [J].
Fan, Zhuang-Jun ;
Kai, Wang ;
Yan, Jun ;
Wei, Tong ;
Zhi, Lin-Jie ;
Feng, Jing ;
Ren, Yue-ming ;
Song, Li-Ping ;
Wei, Fei .
ACS NANO, 2011, 5 (01) :191-198
[7]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[8]   Reduced graphene oxide/α-Fe2O3 composite nanofibers for application in gas sensors [J].
Guo, Lanlan ;
Kou, Xueying ;
Ding, Mengdi ;
Wang, Chong ;
Dong, Linlin ;
Zhang, Hong ;
Feng, Changhao ;
Sun, Yanfeng ;
Gao, Yuan ;
Sun, Peng ;
Lu, Geyu .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 244 :233-242
[9]   Lithium Storage Using Conversion Reaction in Maghemite and Hematite [J].
Hariharan, Srirama ;
Saravanan, Kuppan ;
Balaya, Palani .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (09) :A132-A134
[10]  
He G., 2016, ADV SCI, V4