A novel Cr-doped Al2O3-SiC-ZrC composite coating for ablative protection of C/C-ZrC-SiC composites

被引:25
作者
Peng, Zheng [1 ]
Sun, Wei [1 ]
Xiong, Xiang [1 ]
Xu, Yonglong [1 ]
Chen, Yuntian [1 ]
机构
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
基金
美国国家科学基金会;
关键词
C/C-ZrC-SiC; Al2O3-SiC-ZrC composite coating; Cr doped; Ablation; CARBON/CARBON COMPOSITES; OXIDATION BEHAVIOR; MICROSTRUCTURE; INFILTRATION; RESISTANCE; SYSTEM;
D O I
10.1016/j.jeurceramsoc.2018.02.015
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A novel Cr-doped Al2O3-SiC-ZrC coating systemis proposed to further improve the ablation resistance of C/CZrC-SiC composites. Our approach combines low pressure plasma spray method with slurry impregnation of ZrCr-Si-C to achieve a specially tailored oxide-carbide structure. Results show that the as-prepared coating was dense and crack-free, which effectively promoted the ablation resistance of C/C-ZrC-SiC with the mass and linear ablation rates decreased by 66% and 76% respectively, involving a highly dense protective structure of AlxCr2-xO3-SiO2-ZrO2 formed during ablation. The compact and continuous multi-oxide scale with "ZrO2-rosette" skeleton intricated with A1(1.96)Cr(0.04)O(3) was evidenced in the ablation center.
引用
收藏
页码:2897 / 2902
页数:6
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