Kinetics of J-aggregation of a thiacarbocyanine dye in aqueous solution:: Novel aggregate mediated by alcohols and metal ions

被引：13

作者：

Chibisov, Alexander K.

Slavnova, Tatyana D.

Goerner, Helmut ^{[1
]}

机构：

[1] Max Planck Inst Bioanorgan Chem, D-45413 Mulheim, Germany

[2] Russian Acad Sci, Ctr Photochem, Moscow 119421, Russia

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 424卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2006.04.075

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of formation of J-aggregates induced by mono-, di- and trivalent metal ions was studied for 3,3'-di(gamma-sulfopropyl)-5-methoxy-4',5'-benzo-9-ethylthiacarbocyanine in aqueous solution in the presence of organic solvents, e.g.. acetonitrile, where the rate is strongly decreased. A novel intermediate aggregate (I-aggregate) was observed, when a metal ion was added to the thiacarbocyanine dye in a mixture of water with alcohols. The I- and J-aggregates are formed front the dimers. The kinetics of formation of the I-aggregate depend on the concentrations of alcohol and metal ions and its decay matches the formation of the modified J-aggregate. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：307 / 311

页数：5

共 27 条

[1] Photo- and thermoinitiated formation of J and H aggregates in amorphous dispersions of a carbocyanine dye
Alfimov, MV
Shtykova, AA
Razumov, VF
[J]. HIGH ENERGY CHEMISTRY, 2006, 40 (01) : 18 - 21
[2] AVDEEVA VI, 2003, DOKL AKAD NAUK, V389, P62
[3] Reply to comment on 'Kinetics of salt-induced J-aggregation of an anionic thiacarbocyanine dye in aqueous solution'
Chibisov, AK
Görner, H
Slavnova, TD
[J]. CHEMICAL PHYSICS LETTERS, 2005, 401 (4-6) : 592 - 593
[4] Kinetics of salt-induced J-aggregation of an anionic thiacarbocyanine dye in aqueous solution
Chibisov, AK
Görner, H
Slavnova, TD
[J]. CHEMICAL PHYSICS LETTERS, 2004, 390 (1-3) : 240 - 245
[5] Photoprocesses in dimers of thiacarbocyanines
Chibisov, AK
Zakharova, GV
Görner, H
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (07) : 1455 - 1460
[6] DALTROZZO E, 1974, PHOTOGR SCI ENG, V18, P441
[7] Molecular segregation observed in a concentrated alcohol-water solution
Dixit, S
Crain, J
Poon, WCK
Finney, JL
Soper, AK
[J]. NATURE, 2002, 416 (6883) : 829 - 832
[8] Layer-by-layer self-assembly of polyelectrolyte and water soluble cyanine dye
Fukumoto, H
Yonezawa, Y
[J]. THIN SOLID FILMS, 1998, 327 : 748 - 751
[9] Kinetics of J-aggregation of cyanine dyes in the presence of gelatin
Görner, H
Chibisov, AK
Slavnova, TD
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (09) : 3917 - 3923
[10] DNA-templated assembly of helical cyanine dye aggregates: A supramolecular chain polymerization
Hannah, KC
Armitage, BA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (11) : 845 - 853

← 1 2 3 →