Mechanical performance of reactive-air-brazed (RAB) ceramic/metal joints for solid oxide fuel cells at ambient temperature

Mechanical integrity of the sealants in planar SOFC stacks is a key prerequisite for reliable operation. in this respect joining with metals rather than brittle glass-ceramics is considered to have advantages. Hence, as one of the joining solutions for SOFCs of planar design, reactive air brazing of ceramic cells into metallic frames gains increasing interest. Fracture experiments are carried out to characterize fracture energy and failure mechanisms of silver-based reactive-air-brazes, used for joining the zirconia electrolytes of anode supported planar cells with metallic Crofer22APU frames. The specimens are mechanically tested in notched beam bending geometry. In-situ observation in optical and SEM resolution reveals specific failure mechanisms. The influence of braze formulation and associated interfacial reactions on the crack path location is addressed. Discussion of the results focuses in particular on the role of oxide scale formation. (C) 2008 Elsevier B.V. All rights reserved.