Efficient total syntheses and structural verification of both diospongins A and B via a common δ-lactone intermediate

被引：67

作者：

Sawant, Kailas B. ^{[1
]}

Jennings, Michael P. ^{[1
]}

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 20期

关键词：

D O I：

10.1021/jo061296f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Chemical Equation Presented) The total syntheses of the two aryl C-glycoside natural products diospongins A and B are described. The key reactions involved stereoselective reductions of the appropriate oxocarbenium cations that were derived from a common δ-lactone intermediate. © 2006 American Chemical Society.

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页码：7911 / 7914

页数：4

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