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Analysis of the electron-vibrational interaction in the 5d states of Eu2+ ions in LiSrPO4 host matrix
被引:13
|作者:
Nair, Govind B.
[1
]
Swart, H. C.
[1
]
Dhoble, S. J.
[2
]
机构:
[1] Univ Free State, Dept Phys, POB 339, ZA-9300 Bloemfontein, South Africa
[2] RTM Nagpur Univ, Dept Phys, Nagpur 440033, Maharashtra, India
基金:
新加坡国家研究基金会;
关键词:
Sol-gel;
Electron-vibrational interaction (EVI);
Eu-2(+) ions;
4f-5d transitions;
PHOSPHOR;
ENERGY;
CE3+;
D O I:
10.1016/j.jlumin.2019.116564
中图分类号:
O43 [光学];
学科分类号:
070207 ;
0803 ;
摘要:
Different concentrations of Eu2+ doped LiSrPO4 phosphors were synthesized by a sol-gel/Pechini method. The photoluminescence (PL) excitation and emission spectra were recorded for all the samples and the optimum photoluminescence (PL) intensity was obtained for the 5 mol% sample. The Rietveld refinement method was performed on the optimum sample structure. Electron-vibrational interaction parameters were evaluated using a spectrum-fitting method. The International Commission on Illumination chromaticity coordinates were located in the blue region, indicating the possibility of employing this phosphor as a blue-emitting component in Ultraviolet-pumped light emitting diode.
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页数:10
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