Preparation and characterization of polystyrene/graphite composite prepared by cationic grafting polymerization

被引：95
作者：
Wang, WP
Pan, CY
机构：
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China
[2] Hefei Univ Technol, Dept Chem Engn, Hefei 230009, Anhui, Peoples R China
来源：
POLYMER | 2004年 / 45卷 / 12期
关键词：
composite; polystyrene; expanded graphite;
D O I：
10.1016/j.polymer.2004.04.023
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new graphite/polystyrene composite was produced with cationic grafting polymerization of styrene initiated by CO+ClO4- group on the surface of expanded graphite (EG). The structures of EG and the graphite/polystyrene composite were studied with SEM and optical micrograph. The spectra of XRD and IR were used not only for confirming whether the polymerization reaction took place, but also for determining whether the polystyrene in the composite covered the surface of EG particles or intercalated into EG particles. The electrical conductivity, thermal phase transitions and mechanical properties were also discussed. (C) 2004 Published by Elsevier Ltd.
引用
收藏
页码：3987 / 3995
页数：9
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