Synthesis, structure and catalytic properties of [Ru(dppp)2(CH3CN)Cl][BPh4] and isolation of catalytically active [Ru(dppp)2Cl][BPh4]: ruthenium catalysed alkyne homocoupling and tandem alkyne-azide cycloaddition

被引：17

作者：

Das, Uttam Kumar ^{[1
]}

Jena, Rajesh K. ^{[1
]}

Bhattacharjee, Manish ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

RSC ADVANCES | 2014年 / 4卷 / 42期

关键词：

CARBOXYLIC-ACIDS; TERMINAL ALKYNES; SPECTROSCOPIC PROPERTIES; TRANSFER HYDROGENATION; COMPLEXES; LIGAND; FUNCTIONALIZATION; STRATEGY; CHLORIDE; HYDRIDE;

D O I：

10.1039/c4ra01411a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound, [Ru(dppp)(2)(CH3CN)Cl][BPh4] (1) has been synthesised from the precursor complex, [Ru(PPh3)(3)Cl-2]. The complex has been structurally characterised. The complex has been found to be an efficient catalyst for the homocoupling of alkynes in the presence of silver salts. The complex can also catalyse homocoupling of alkynes and subsequent alkyne-azide cycloaddition. The catalytically active species, [Ru(dppp)(2)Cl][BPh4] (2) and one of the intermediate complexes, [Ru(dppp)(2)(CCPh)(2)] (6), have been isolated and structurally characterised.

引用

页码：21964 / 21970

页数：7

共 19 条

[1] Ruthenium cationic species for transfer hydrogenation of aldehydes:: Synthesis and catalytic properties of [(PPh3)2Ru(CH3CN)3Cl]+[A]- {A = BPh4 or ClO4} and structure of [(PPh3)2Ru(CH3CN)3Cl]+[BPh4l-
Naskar, S
Bhattacharjee, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (21-22) : 5006 - 5010
[2] Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes
Das, Uttam Kumar
Bhattacharjee, Manish
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 700 : 78 - 82
[3] Synthesis and structure of [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4] and it's catalytic property towards regioselective and stereoselective allylation of phenols
Sinha, Abhilasha
Khatua, Snehadrinarayan
Bhattacharjee, Manish
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 770 : 116 - 120
[4] ACTIVATION OF DICHLOROMETHANE BY PALLADIUM(0) AND PLATINUM(0) PHOSPHINE COMPLEXES - SYNTHESIS AND STRUCTURE OF [(N(CH2CH2PPH2)3)PO(CH2CL)](BPH4), [(N(CH2CH2PPH2)3)PT(CH2CI)](BPH4)
GHILARDI, CA
MIDOLLINI, S
MONETI, S
ORLANDINI, A
RAMIREZ, JA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (05) : 304 - 306
[5] RUTHENIUM THIOETHER CHEMISTRY - THE SYNTHESIS AND STRUCTURE OF A HOST GUEST COMPLEX [RU([9]ANES3)2][BPH4]2.2ME2SO, AND OF [RU([9]ANES3)2]-[BPH4]2.2MENO2 AND [RU([18]ANES6)][BPH4]2([9]ANES3 = 1,4,7-TRITHIACYCLONONANE, [18]ANES6 = 1,4,7,10,13,16-HEXATHIACYCLO-OCTADECANE)
BELL, MN
BLAKE, AJ
HOLDER, AJ
HYDE, TI
SCHRODER, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (12): : 3841 - 3847
[6] Synthesis, structure, and properties of the η2 P O-chelated mono(ether-phosphine)ruthenium complex [Cp*Ru(CO)(P O)][BPh4]
Lindner, E.
Haustein, M.
Mayer, H.A.
Gierling, K.
Fawzi, R.
Steimann, M.
Organometallics, 1995, 14 (05):
[7] RUTHENIUM(II) SOLVENTO COMPLEXES CONTAINING THE TRIPOD-LIKE LIGANDS MEC(CH2PPH2)3, MEC(CH2ASPH2)3 AND THEIR REACTIONS WITH CARBON-MONOXIDE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RU2(MU-CL)3(MEC(CH2PPH2)3)2][BPH4]
RHODES, LF
SORATO, C
VENANZI, LM
BACHECHI, F
INORGANIC CHEMISTRY, 1988, 27 (04) : 604 - 610
[8] INFLUENCE OF THE SOLVENT ON THE REACTIVITY OF CO-1-X(PME3)3 WITH ETHYLENE - SYNTHESIS, MOLECULAR AND SOLID-STATE STRUCTURE OF "[CO(PME3)3(C2H4)(CH3-CN)]BPH4,CH3CN
CAPELLE, B
DARTIGUENAVE, M
DARTIGUENAVE, Y
BEAUCHAMP, A
INORGANICA CHIMICA ACTA-ARTICLES, 1980, 40 (02): : X127 - X127
[9] Synthesis and properties of five-co-ordinate complexes of ruthenium and osmium containing the bulky phosphine 1,2-bis(diisopropylphosphino)ethane (dippe).: Crystal structure of [Ru(SPh)(dippe)2]-[BPh4]
de los Rios, I
Jimenez-Tenorio, M
Puerta, MC
Salcedo, I
Valerga, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (23): : 4619 - 4624
[10] The synthesis and electrochemical behavior of ruthenium(III) bipyridine complexes:: [Ru(dcbpy)Cl4]- (dcbpy-4,4′-dicarboxylic acid-2,2′-bipyridine) and [Ru(bpy)Cl3L] (L = CH3OH, PPh3, 4,4′-bpy, CH3CN)
Eskelinen, E
Da Costa, P
Haukka, M
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 579 (02) : 257 - 265

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