Compatibilization of conductive polyethylene/polyaniline blends

被引:14
作者
Annala, Minna [1 ]
Lofgren, Barbro [1 ]
机构
[1] Aalto Univ, Lab Polymer Technol, FIN-02015 Helsinki, Finland
关键词
blends; compatibilization; functionalized polyethylene; polyaniline;
D O I
10.1002/mame.200600071
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The compatibilization of polyethylene/polyaniline (PE/PANI) blends and the preparation of plasticized PANI/camphorsulfonic acid (CSA) complexes suitable for melt blending were studied. Rheological properties of the components essentially affected the morphology of the blend and thereby the electrical conductivity. The hydrogen bonds between the PANI complex and the functionalized metallocene PE used as compatibilizer compensated the unfavorable viscosities of the components. Mechanical properties of PE/PANI blends were improved, and electrical conductivity of the blends remained the same or increased through addition of functionalized metallocene polyethylene. Plasticized PANI/CSA complex with good electrical conductivity was successfully prepared.
引用
收藏
页码:848 / 857
页数:10
相关论文
共 23 条
[11]  
KARNA T, 1994, Patent No. 582919
[12]   Functionalization of polyethylene with silane comonomers [J].
Lipponen, S ;
Seppälä, J .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (09) :1303-1308
[13]   THE CONCEPT OF SECONDARY DOPING AS APPLIED TO POLYANILINE [J].
MACDIARMID, AG ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1994, 65 (2-3) :103-116
[14]   SECONDARY DOPING IN POLYANILINE [J].
MACDIARMID, AG ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1995, 69 (1-3) :85-92
[15]   Enhanced adhesive properties of polypropylene through copolymerization with 10-undecen-1-ol [J].
Paavola, S ;
Uotila, R ;
Löfgren, B ;
Seppala, JV .
REACTIVE & FUNCTIONAL POLYMERS, 2004, 61 (01) :53-62
[16]   Improved conductivity of films of ultra high molecular weight polyethylene and polyaniline blends prepared from an m-cresol/decaline mixture [J].
Valenciano, GR ;
Job, AE ;
Mattoso, LHC .
POLYMER, 2000, 41 (12) :4757-4760
[17]  
WAN P, 1999, Patent No. 5908898
[18]   Secondary doping phenomena of two conductive polyaniline composites [J].
Xie, HQ ;
Ma, YM ;
Guo, JS .
SYNTHETIC METALS, 2001, 123 (01) :47-52
[19]   Preparation of low density polyethylene-based polyaniline conducting polymer composites with low percolation threshold via extrusion [J].
Yang, JP ;
Rannou, P ;
Planes, J ;
Pron, A ;
Nechtschein, M .
SYNTHETIC METALS, 1998, 93 (03) :169-173
[20]   Electrically conductive, melt-processed ternary blends of polyaniline/dodecylbenzene sulfonic acid, ethylene/vinyl acetate, and low-density polyethylene [J].
Zhang, QH ;
Wang, XH ;
Chen, DJ ;
Jing, XB .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (20) :3750-3758