The effect of Ce3+ ions on the spectral and decay characteristics of luminescence phosphate-borate glasses doped with rare-earth ions

被引:1
|
作者
Valiev, D. T. [1 ]
Polisadova, E. F. [1 ]
Belikov, K. N. [2 ]
Egorova, N. L. [2 ]
机构
[1] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia
[2] Natl Acad Sci Ukraine, Inst Single Crystals, Kharkiv 61001, Russia
关键词
ENERGY-TRANSFER;
D O I
10.1134/S0030400X14050282
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The luminescent characteristics of Li2O-B2O3-P2O5-CaF2 (LBPC) glasses doped with Gd3+ and Tb3+ ions and codoped with Ce3+ are studied by pulsed optical spectrometry under electron beam excitation. It is found that in glass with Ce3+ and Gd3+ ions a decrease in the decay time of gadolinium luminescence in the 312-nm band ((6) P (J) -> (8) S (7/2)) was observed. It is shown that in the glass LBPC: Tb, Ce, an increase in the emission intensity in the main radiative transitions in terbium ion was observed. In the kinetics of luminescence band 545 nm of LBPC: Tb, Ce glasses, is present stage of buildup, the character of which changes with the doped of Ce3+ ions. The mechanism of energy transfer in LBP glasses doped with rare elements is discussed.
引用
收藏
页码:677 / 682
页数:6
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