Iron(III) promoted degradation of 2,6-dimethylphenol in aqueous solution.

被引：26

作者：

Mazellier, P

Bolte, M

机构：

[1] Lab. Photochimie Molec. M., CNRS - Univ. Biaise Pascal - UMR

来源：

CHEMOSPHERE | 1997年 / 35卷 / 10期

关键词：

D O I：

10.1016/S0045-6535(97)00296-8

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The redox process that occurs between 2,6-dimethylphenol (DMP) and iron(III) in aqueous solution was investigated The reaction requires an excess in Fe(OH)(2+), the iron(III) monomeric species present in the solution. The ratio [Fe(OH)(2+)]/[DMP] has to be higher than 1.5 approximately. The reaction is of first order with respect to DMP. The major product is 3,3',5,5'-tetramethyldiphenoquinone together with DMP dimer and 2,6-dimethylbenzoquinone. The formation of the identified products represents 80 to 85% of DMP disappearance. (C) 1997 Elsevier Science Ltd.

引用

页码：2181 / 2192

页数：12

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