Synthesis and characterization of mono and polymeric cyclopalladated compounds: Crystal and molecular structure of [{Pd(dmba)(ONO2)}2(μ-pz)] • H2O (pz = pyrazine)

被引：8

作者：

Ananias, Sandra R. ^{[1
,2
,3
]}

Ferreira, Janaina G. ^{[1
,3
]}

Mauro, Antonio E. ^{[3
]}

Netto, Adelino V. G. ^{[3
]}

Klein, Stanlei I. ^{[3
]}

Santos, Regina H. A. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, Dept Quim & Fis Mol, BR-13560970 Sao Paulo, Brazil

[2] UNESP, Fac Ciencias, Dept Quim, BR-17033360 Bauru, SP, Brazil

[3] UNESP, Inst Quim, Dept Quim Geral & Inorganca, BR-14801970 Araraquara, SP, Brazil

来源：

POLYHEDRON | 2009年 / 28卷 / 02期

基金：

巴西圣保罗研究基金会;

关键词：

Cyclometallated; Palladium; Nitro compounds; X-RAY; PALLADIUM(II) COMPOUNDS; BUILDING-BLOCKS; LIQUID-CRYSTALS; SCHIFF-BASES; COMPLEXES; COORDINATION; LIGANDS; REDUCTION; CHEMISTRY;

D O I：

10.1016/j.poly.2008.10.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the treatment of cyclometallated dimer [Pd(dmba)(mu-Cl)](2) (dmba = N,N-dimethylbenzylamine) with AgNO3 and acetonitrile the result was the monomeric cationic precursor [Pd(dmba)(NCMe)(2)](NO3) (NCMe=acetonitrile) (1). Compound 1 reacted with m-nitroaniline (m-NAN) and pirazine (pz), originating [Pd(dmba)(ONO2)(m-NAN)] (2) and [{Pd(dmba)(ONO2)}(2)(mu-pz)] center dot H2O (3), respectively. These compounds were characterized by elemental analysis, IR and NMR spectroscopy. The IR spectra of (2-3) display typical bands of monodentade O-bonded nitrate groups, whereas the NMR data of 3 are consistent with the presence of bridging pyrazine ligands. The structure of compound 3 was determined by Xray diffraction analysis. This packing consists of a supramolecular chain formed by hydrogen bonding between the water molecule and nitrato ligands of two consecutive [Pd-2(dmba)(2)(ONO2)2(mu-pz)] units. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：286 / 290

页数：5

共 59 条

[21] Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].

Fujita, M .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425

[22] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[23]

GODQUIN AMG, 1998, COORDIN CHEM REV, V178, P1485

[24] CONFIGURATION INTERACTION STUDIES OF GROUND AND EXCITED STATES OF POLYATOMIC MOLECULES .2. ELECTRONIC STATES AND SPECTRUM OF PYRAZINE [J].

HACKMEYER, M ;

WHITTEN, JL .

JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (09) :3739-+

[25] SYNTHESIS AND CYTOTOXICITY OF SOME CYCLOMETALATED PALLADIUM COMPLEXES [J].

HIGGINS, JD ;

NEELY, L ;

FRICKER, S .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1993, 49 (02) :149-156

[26] LARGE SELF-ASSEMBLED ORGANOPALLADIUM SPHERES [J].

HUCK, WTS ;

VANVEGGEL, FCJM ;

KROPMAN, BL ;

BLANK, DHA ;

KEIM, EG ;

SMITHERS, MMA ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (31) :8293-8294

[27]

HUCK WTS, 1993, ANGEW CHEM INT EDIT, V32, P392

[28] Crystal structure of (2,2'-bipyrimidine)-dinitratopalladium(II) acetone solvate [J].

Hudgens, T ;

Johnson, D ;

Cordes, W ;

Barclay, T ;

Jeter, D .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1997, 27 (04) :247-250

[29] Dihydrogen reduction of nitroorganics, alkenes, alkynes, and Schiff bases using polymer-anchored orthometalated Schiff-base complexes of palladium(II) as catalysts [J].

Islam, SM ;

Bose, A ;

Palit, BK ;

Saha, CR .

JOURNAL OF CATALYSIS, 1998, 173 (02) :268-281

[30] THE VERSATILE CHEMISTRY OF 1,4-DIAZINES - ORGANIC, INORGANIC AND BIOCHEMICAL ASPECTS [J].

KAIM, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1983, 22 (03) :171-190

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