Synthesis and characterization of mono and polymeric cyclopalladated compounds: Crystal and molecular structure of [{Pd(dmba)(ONO2)}2(μ-pz)] • H2O (pz = pyrazine)

被引：8

作者：

Ananias, Sandra R. ^{[1
,2
,3
]}

Ferreira, Janaina G. ^{[1
,3
]}

Mauro, Antonio E. ^{[3
]}

Netto, Adelino V. G. ^{[3
]}

Klein, Stanlei I. ^{[3
]}

Santos, Regina H. A. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, Dept Quim & Fis Mol, BR-13560970 Sao Paulo, Brazil

[2] UNESP, Fac Ciencias, Dept Quim, BR-17033360 Bauru, SP, Brazil

[3] UNESP, Inst Quim, Dept Quim Geral & Inorganca, BR-14801970 Araraquara, SP, Brazil

来源：

POLYHEDRON | 2009年 / 28卷 / 02期

基金：

巴西圣保罗研究基金会;

关键词：

Cyclometallated; Palladium; Nitro compounds; X-RAY; PALLADIUM(II) COMPOUNDS; BUILDING-BLOCKS; LIQUID-CRYSTALS; SCHIFF-BASES; COMPLEXES; COORDINATION; LIGANDS; REDUCTION; CHEMISTRY;

D O I：

10.1016/j.poly.2008.10.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the treatment of cyclometallated dimer [Pd(dmba)(mu-Cl)](2) (dmba = N,N-dimethylbenzylamine) with AgNO3 and acetonitrile the result was the monomeric cationic precursor [Pd(dmba)(NCMe)(2)](NO3) (NCMe=acetonitrile) (1). Compound 1 reacted with m-nitroaniline (m-NAN) and pirazine (pz), originating [Pd(dmba)(ONO2)(m-NAN)] (2) and [{Pd(dmba)(ONO2)}(2)(mu-pz)] center dot H2O (3), respectively. These compounds were characterized by elemental analysis, IR and NMR spectroscopy. The IR spectra of (2-3) display typical bands of monodentade O-bonded nitrate groups, whereas the NMR data of 3 are consistent with the presence of bridging pyrazine ligands. The structure of compound 3 was determined by Xray diffraction analysis. This packing consists of a supramolecular chain formed by hydrogen bonding between the water molecule and nitrato ligands of two consecutive [Pd-2(dmba)(2)(ONO2)2(mu-pz)] units. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：286 / 290

页数：5

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