Optical Property of Dy3+-and Ce3+-Doped Si-B-Na-Sr Glasses

被引:16
作者
He, Wanyi [1 ]
Wang, Xiangfu [1 ]
Zheng, Jin [1 ]
Yan, Xiaohong [1 ,2 ]
机构
[1] Nanjing Univ Post & Telecommun, Coll Elect Sci & Engn, Nanjing 210046, Jiangsu, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Sci, Nanjing 211106, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
SPECTROSCOPIC PROPERTIES; ENERGY-TRANSFER; FLUOROPHOSPHATE GLASSES; LUMINESCENCE PROPERTIES; FLUOROBORATE GLASSES; GERMANATE GLASSES; BORATE GLASSES; ALKALI BORATE; PHOTOLUMINESCENCE; ABSORPTION;
D O I
10.1111/jace.12973
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Novel Dy3+ and Ce3+ doped Si-B-Na-Sr (SBNS) glasses were synthesized by melt-quenching technique. Excited by 327nm, the 0.5Dy3+-and 0.5Ce3+-doped SBNS exhibits white emission with Commission Internationale de L'Eclairage coordinates of (0.308, 0.280). Basic optical characterizations have been performed by measuring the absorption and emission spectra and calculating Judd-Ofelt intensity parameters, radiative probability, luminescence branching ratio, cross sections, and effective bandwidth. The Judd-Ofelt parameters 2, 4, and 6 indicate a high asymmetrical environment and covalent environment in the optical glass. The emission color of Ce3+ and Dy3+ codoped transparent glass can be tuned from blue to white through energy transfer from Ce3+ to Dy3+ ions. The resulting glass may have potential application in white-light-emitting source.
引用
收藏
页码:1750 / 1755
页数:6
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