Cobalt-free nickel-metal hydride battery for industrial applications

被引:20
|
作者
Takasaki, Tomoaki [1 ,2 ]
Nishimura, Kazuya [2 ]
Saito, Makoto [1 ]
Fukunaga, Hiroshi [2 ]
Iwaki, Tsutomu [1 ]
Sakai, Tetsuo [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Ubiquitous Energy Devices, Ikeda, Osaka 5638577, Japan
[2] Kawasaki Heavy Ind Co Ltd, GIGACELL Battery Ctr, Rolling Stock Co, Akashi, Hyogo 6738666, Japan
关键词
Nickel-metal hydride battery; Cobalt-free; Industrial application; HYDROGEN CAPACITY; ALLOYS; ELECTRODE;
D O I
10.1016/j.jallcom.2013.01.092
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A cobalt-free (Co-free) RE0.9Mg0.1Ni3.9Al0.2 alloy (RE: rare earth) was prepared for use in a nickel-metal hydride (Ni-MH) battery. The use of the alloy as the negative electrode of the Ni-MH battery effectively improved the high-rate discharge and suppressed the self-discharge compared to the conventional AB(5)-type alloy. Moreover, carbon-coated Ni(OH)(2) has been developed to produce a Co-free Ni-MH battery. This material exhibits a capacity retention comparable to that of the conventional CoOOH-coated Ni(OH)(2). A 205 A h Co-free Ni-MH battery cell was constructed using the Co-free materials, and this cell exhibited a good high-rate discharge performance. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:S378 / S381
页数:4
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