A remarkably stable copper(I) ethylene complex:: synthesis, spectroscopy and structure

被引：94

作者：

Straub, BF ^{[1
]}

Eisenträger, F ^{[1
]}

Hofmann, P ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 24期

关键词：

D O I：

10.1039/a907928i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel copper(I) ethylene complex [(Bu2P)-P-t(NSiMe3)(2)-kappa(2)N]Cu(eta(2)-C2H4) and its norbornene analogue have been synthesized and characterized and their solid state structures determined.

引用

页码：2507 / 2508

页数：2

共 18 条

[1] ELECTRON-DIFFRACTION STUDY OF STRUCTURES OF C2H4 AND C2D4 [J].

BARTELL, LS ;

ROTH, EA ;

HOLLOWEL.CD ;

KUCHITSU, K ;

YOUNG, JE .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (08) :2683-&

[2] NMR INVESTIGATION OF ACETYLENE-CU(I)-PI-COMPLEX IN HOMOGENEOUS AQUEOUS-SOLUTION [J].

BORG, A ;

LINDBLOM, T ;

VESTIN, R .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1975, 29 (05) :475-480

[3] Kinetics of the BpCu-catalyzed carbene transfer reaction (Bp equals dihydridobis(1-pyrazolyl)borate).: Is a 14-electron species the real catalyst for the general copper-mediated olefin cyclopropanation? [J].

Díaz-Requejo, MM ;

Belderrain, TR ;

Nicasio, MC ;

Prieto, F ;

Pérez, PJ .

ORGANOMETALLICS, 1999, 18 (14) :2601-2609

[4] BpCu-catalyzed cyclopropanation of olefins: A simple system that operates under homogeneous and heterogeneous conditions (Bp=dihydridobis(pyrazolyl)borate) [J].

Diaz-Requejo, MM ;

Nicasio, MC ;

Perez, PJ .

ORGANOMETALLICS, 1998, 17 (14) :3051-3057

[5]

ECKER JR, 1995, SCIENCE, V268, P667, DOI 10.1126/science.7732375

[6]

FRIEDBOLIN H, 1992, BASIC 1 2 DIMENSIONA

[7] AN NMR INVESTIGATION OF THE REACTION BETWEEN CINNAMIC ACID-ESTERS AND LITHIUM DIMETHYLCUPRATE - INITIAL FORMATION OF AN OLEFIN-COPPER PI-COMPLEX [J].

HALLNEMO, G ;

OLSSON, T ;

ULLENIUS, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (01) :133-144

[8]

HOFMANN P, 1987, Z NATURFORSCH B, V42, P395

[9]

KLAUI W, 1988, ORGANOMETALLICS, V7, P1357

[10]

Mori S, 1999, CHEM-EUR J, V5, P1534

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