Bis-cyclometallated gold(III) complexes as efficient catalysts for synthesis of propargylamines and alkylated indoles

被引：47
作者：
Ko, Hok-Ming
Kung, Karen Ka-Yan
Cui, Jian-Fang
Wong, Man-Kin [1 ]
机构：
[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Kowloon, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 78期
关键词：
GOLD CATALYSIS; IMINOPHOSPHORANE COMPLEXES; C-C; AMINES; SUBSTITUTION; REACTIVITY; ARENES;
D O I：
10.1039/c3cc44828b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stable bis-cyclometallated gold(III) complexes were developed as efficient catalysts for organic transformation reactions by using two strategies: (1) construction of distorted square planar gold(III) complexes and (2) dual catalysis by gold(III) complexes and silver salts.
引用
收藏
页码：8869 / 8871
页数：3
相关论文
共 44 条
[1]   Organogold(III) iminophosphorane complexes as efficient catalysts in the addition of 2-methylfuran and electron-rich arenes to methyl vinyl ketone [J].
Aguilar, David ;
Contel, Maria ;
Navarro, Rafael ;
Urriolabeitia, Esteban P. .
ORGANOMETALLICS, 2007, 26 (18) :4604-4611
[2]   Gold(III) iminophosphorane complexes as catalysts in C-C and C-O bond formations [J].
Aguilar, David ;
Contel, Maria ;
Navarro, Rafael ;
Soler, Tatiana ;
Urriolabeitia, Esteban P. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (04) :486-493
[3]   Platinnm-catalyzed multistep reactions of indoles with alkynyl alcohols [J].
Bhuvaneswari, Sivakolundu ;
Jeganmohan, Masilamani ;
Cheng, Chien-Hong .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (29) :8285-8293
[4]   Synthesis, characterisation and substitution reactions of gold(III) C,N-chelates [J].
Bonnardel, PA ;
Parish, RV ;
Pritchard, RG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (15) :3185-3193
[5]   Gold-Catalyzed Carbon-Heteroatom Bond-Forming Reactions [J].
Corma, A. ;
Leyva-Perez, A. ;
Sabater, Maria J. .
CHEMICAL REVIEWS, 2011, 111 (03) :1657-1712
[6]   New pyridine ONN-pincer gold and palladium complexes: Synthesis, characterization and catalysis in hydrogenation, hydrosilylation and C-C cross-coupling reactions [J].
Debono, N. ;
Iglesias, M. ;
Sanchez, F. .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (16) :2470-2476
[7]   Gold(III) chloride catalyzed domino processes with isobenzopyrylium cation intermediates [J].
Dyker, G ;
Hildebrandt, D ;
Liu, JH ;
Merz, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4399-4402
[8]   Olefination of ketones using a gold(III)-catalyzed Meyer-Schuster rearrangement [J].
Engel, Douglas A. ;
Dudley, Gregory B. .
ORGANIC LETTERS, 2006, 8 (18) :4027-4029
[9]   Chemical and biological studies of the dichloro(2-phenylpyridine) gold(III) complex and its derivatives [J].
Fan, DM ;
Yang, CT ;
Ranford, JD ;
Lee, PF ;
Vittal, JJ .
DALTON TRANSACTIONS, 2003, (13) :2680-2685
[10]   Intra- and intermolecular reactions of indoles with alkynes catalyzed by gold [J].
Ferrer, Catalina ;
Amijs, Catelijne H. M. ;
Echavarren, Antonio M. .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (05) :1358-1373
12345