Facile epoxidation of α, β-unsaturated ketones with urea-2,2-dihydroperoxypropane as a new oxidant

被引：6
作者：
Khosravi, Kaveh [1 ]
Naserifar, Shirin [1 ]
机构：
[1] Arak Univ, Dept Chem, Fac Sci, Arak 3815688349, Iran
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2017年 / 14卷 / 02期
关键词：
Epoxidation; Gem-dihydroperoxide; Urea-2,2-dihydroperoxypropane; alpha; beta-unsaturated ketones; Epoxide; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; ENANTIOSELECTIVE EPOXIDATION; SYNTHETIC APPLICATIONS; EFFICIENT EPOXIDATION; GEM-DIHYDROPEROXIDES; HYDROGEN-PEROXIDE; CATALYST; OLEFINS; CONVERSION; REAGENT;
D O I：
10.1007/s13738-016-0980-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Various aromatic alpha, beta-unsaturated ketones were successfully transformed into their corresponding epoxides using urea-2,2-dihydroperoxypropane as the oxygen source for the first time. The reactions were carried out under mild alkaline conditions at room temperature in high yields and short reaction times. [GRAPHICS] .
引用
收藏
页码：323 / 328
页数：6
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