Hydrodynamic voltammetry with channel microband electrodes: The simulation of voltammetric waveshapes

被引：33

作者：

Bidwell, MJ ^{[1
]}

Alden, JA ^{[1
]}

Compton, RG ^{[1
]}

机构：

[1] UNIV OXFORD,PHYS & THEORET CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 417卷 / 1-2期

关键词：

channel microband electrodes; hydrodynamic voltammetry; simulation; strongly implicit procedure; multigrid method MGD1; current-voltage waveshapes;

D O I：

10.1016/S0022-0728(96)04739-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The strongly implicit procedure and the multigrid method MGD1 are used to simulate the steady-state current-voltage response of channel electrodes, including under conditions where diffusional effects in the direction of flow are significant. Reversible, quasi-reversible and irreversible heterogeneous kinetics are all considered.

引用

页码：119 / 128

页数：10

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