Energy Band Regulation in 2D Perovskite Solar Cells

被引：2

作者：

Zhou, Yi ^{[1
]}

Hu, Jingjing ^{[1
]}

Meng, Fanning ^{[1
]}

Liu, Caiyun ^{[1
]}

Gao, Liguo ^{[1
]}

Ma, Tingli ^{[2
,3
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Kitakyushu, Fukuoka 8080196, Japan

[3] China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Peoples R China

来源：

PROGRESS IN CHEMISTRY | 2020年 / 32卷 / 07期

基金：

中国国家自然科学基金;

关键词：

2D perovskite; perovskite solar cells; charge transport; bandgap regulation; energy level alignment; LEAD IODIDE PEROVSKITES; HIGH-EFFICIENCY; QUASI-2-DIMENSIONAL PEROVSKITE; ENHANCED EFFICIENCY; HALIDE PEROVSKITES; THIN-FILMS; PERFORMANCE; STABILITY; CRYSTALLIZATION; DIMENSIONALITY;

D O I：

10.7536/PC191102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perovskite solar cells(PSCs) have achieved more than 25% efficiency in just a decade, which are of great commercial value. This is because the three-dimensional (3D) perovskite (PVK) layer has many advantages, such as suitable bandgap, high absorption coefficient and long electron diffusion length. However, unstability is still an urgent problem to be solved in 3D PSCs. Comparing with 3D perovskite materials, 2D perovskite crystals have recently attracted increasing attention due to some unique properties for improving stability. The hydrophobic bulky alkylammonium cations in 2D perovskite lattices can block the accessible pathways of moisture invasion, making them promising candidates for optoelectronic devices. Meanwhile, due to the tolerance of 2D perovskite to organic and inorganic elements, its chemical composition and energy band also change. This review highlights the importance of energy bands in 2D PSCs and summarizes bandgap regulation and energy level alignment(ELA) of 2D perovskite, which plays an important role in guiding the preparation of high-efficiency and stable low-dimensional perovskite solar cells.

引用

页码：966 / 977

页数：12

共 105 条

[1]

Ahmad S, 2019, JOULE, V3, P794, DOI 10.1016/j.joule.2018.11.026

[2] Enhanced stability in cesium assisted hybrid 2D/3D-perovskite thin films and solar cells prepared in ambient humidity [J].

Ali, Nasir ;

Wang, Xiaoyu ;

Rauf, Sajid ;

Attique, Sanam ;

Khesro, Amir ;

Ali, Shahid ;

Mushtaq, Naveed ;

Xiao, Haibo ;

Yang, Chang Ping ;

Wu, Huizhen .

SOLAR ENERGY, 2019, 189 :325-332

[3]

[Anonymous], 2017, Adv. Funct. Mater, V27, DOI DOI 10.1002/ADFM.201604733

[4] A Review: Thermal Stability of Methylammonium Lead Halide Based Perovskite Solar Cells [J].

Ava, Tanzila Tasnim ;

Al Mamun, Abdullah ;

Marsillac, Sylvain ;

Namkoong, Gon .

APPLIED SCIENCES-BASEL, 2019, 9 (01)

[5] Dimensional Engineering of a Graded 3D-2D Halide Perovskite Interface Enables Ultrahigh Voc Enhanced Stability in the p-i-n Photovoltaics [J].

Bai, Yang ;

Xiao, Shuang ;

Hu, Chen ;

Zhang, Teng ;

Meng, Xiangyue ;

Lin, He ;

Yang, Yinglong ;

Yang, Shihe .

ADVANCED ENERGY MATERIALS, 2017, 7 (20)

[6] High-efficiency tandem perovskite solar cells [J].

Bailie, Colin D. ;

McGehee, Michael D. .

MRS BULLETIN, 2015, 40 (08) :681-685

[7] 23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability [J].

Bush, Kevin A. ;

Palmstrom, Axel F. ;

Yu, Zhengshan J. ;

Boccard, Mathieu ;

Cheacharoen, Rongrong ;

Mailoa, Jonathan P. ;

McMeekin, David P. ;

Hoye, Robert L. Z. ;

Bailie, Colin D. ;

Leijtens, Tomas ;

Peters, Ian Marius ;

Minichetti, Maxmillian C. ;

Rolston, Nicholas ;

Prasanna, Rohit ;

Sofia, Sarah ;

Harwood, Duncan ;

Ma, Wen ;

Moghadam, Farhad ;

Snaith, Henry J. ;

Buonassisi, Tonio ;

Holman, Zachary C. ;

Bent, Stacey F. ;

McGehee, Michael D. .

NATURE ENERGY, 2017, 2 (04)

[8] Thin Films and Solar Cells Based on Semiconducting Two-Dimensional Ruddlesden-Popper (CH3(CH2)3NH3)2(CH3NH3)n-1SnnI3n+1 i Perovskites [J].

Cao, Duyen H. ;

Stoumpos, Constantinos C. ;

Yokoyama, Takamichi ;

Logsdon, Jenna L. ;

Song, Tze-Bin ;

Farha, Omar K. ;

Wasielewski, Michael R. ;

Hupp, Joseph T. ;

Kanatzidis, Mercouri G. .

ACS ENERGY LETTERS, 2017, 2 (05) :982-990

[9] 2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications [J].

Cao, Duyen H. ;

Stoumpos, Constantinos C. ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Kanatzidis, Mercouri G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (24) :7843-7850

[10] Critical role of chloride in organic ammonium spacer on the performance of Low-dimensional Ruddlesden-Popper perovskite solar cells [J].

Chen, Haoran ;

Xia, Yingdong ;

Wu, Bo ;

Liu, Feng ;

Niu, Tingting ;

Chao, Lingfeng ;

Xing, Guichuan ;

Sum, TzeChien ;

Chen, Yonghua ;

Huang, Wei .

NANO ENERGY, 2019, 56 :373-381

← 1 2 3 4 5 6 7 8 9 10 →