Threshold photoelectron spectroscopy of cyanogen bromide

被引：5
|
作者：
Yencha, AJ
Malins, AER
King, GC
机构：
[1] SUNY Albany, Dept Chem, Albany, NY 12222 USA
[2] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
[3] Univ Manchester, Schuster Lab, Dept Phys & Astron, Manchester M13 9PL, Lancs, England
来源：
CHEMICAL PHYSICS LETTERS | 2004年 / 392卷 / 1-3期
关键词：
D O I：
10.1016/j.cplett.2004.05.069
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A high-resolution (2-15 meV) threshold photoelectron (TPE) spectroscopic study of BrCN was performed using synchrotron radiation and a penetrating-field electron spectrometer over the outer valence ionization region of the molecule. Significant differences were found between the TPE spectrum and the published high-resolution (similar to6 meV) HeI photoelectron spectrum of BrCN [Chem. Phys. 212 (1996) 457]. Autoionization of Rydberg states and the 6sigma valence state of BrCN were found to be primarily responsible for the formation of the observed band systems of BrCN+ in this study. (C) 2004 Elsevier B.V. All rights reserved.
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页码：202 / 208
页数：7
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