A bis(μ-alkylperoxo)dinickel(II) complex as a reaction intermediate for the oxidation of the methyl groups of the Me2-tpa ligand to carboxylate and alkoxide ligands

被引：36

作者：

Cho, J ^{[1
]}

Furutachi, H ^{[1
]}

Fujinami, S ^{[1
]}

Suzuki, M ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

nickel; oxidation; peroxides; reaction mechanisms;

D O I：

10.1002/anie.200353637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A radical approach: The reaction of [Ni2(OH)2(Me 2-tpa)2]2+ with H2O2 resulted in the peroxidation of a methyl group of the Me2-tpa ligand to produce a bis(μ-alkylperoxo)dinickel(II) complex (see ORTEP diagram) as a reaction intermediate for further oxidation to carboxylato and alkoxo complexes [Ni(Mel-tpa-COO)]+ and [Ni2(Me1-tpa-CH 2O)2]2+. Me2-tpa=bis[(6-methyl-2- pyridyl)methyl] [(2-pyridyl)methyl]amine.

引用

页码：3300 / 3303

页数：4

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