Nickel-catalysed carboxylation of organoboronates

被引：62
作者：
Makida, Yusuke [1 ]
Marelli, Enrico [1 ]
Slawin, Alexandra M. Z. [1 ]
Nolan, Steven P. [1 ,2 ]
机构：
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] King Saud Univ, Dept Chem, Coll Sci, Riyadh 11451, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 59期
关键词：
CARBON-DIOXIDE; ESTERS; COMPLEXES; CO2; TRANSFORMATION; HALIDES; ACIDS; BOND;
D O I：
10.1039/c4cc03650f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.
引用
收藏
页码：8010 / 8013
页数：4
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