Electrospun PU/PVP/GO Separator for Li-ion Batteries

被引:5
作者
Song, Kedong [1 ]
Zhang, Ping [1 ]
Huang, Yuting [1 ]
Xu, Fu [1 ]
Ding, Yanhuai [1 ]
机构
[1] Xiangtan Univ, Inst Rheol Mech, Xiangtan 411105, Peoples R China
基金
中国国家自然科学基金;
关键词
Composite; Separator; Electrochemical performance; Li-storage; NANOFIBROUS SEPARATORS; POLYMER ELECTROLYTE; HIGH-PERFORMANCE;
D O I
10.1007/s12221-019-8883-2
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Polyurethane (PU) has been intensively studied as a promising separator material for Li-ion batteries (LIBs). However, poor dimensional stability and low liquid-electrolyte wettability of pure PU separator restrict its application in LIBs. Here polyvinyl pyrrolidone (PVP) and graphene oxide were employed to enhance the thermal stability, mechanical performance and liquid-electrolyte compatibility of PU separator. High anodic stability above 5.25 V was reached in PU/PVP/GO separator, fully compatible with the high-voltage cathode materials. The electrochemical characterization indicates PU/PVP/GO membrane is a promising separator for advanced LIBs.
引用
收藏
页码:961 / 965
页数:5
相关论文
共 20 条
  • [1] Nitrogen-Doped Carbon for Sodium-Ion Battery Anode by Self-Etching and Graphitization of Bimetallic MOF-Based Composite
    Chen, Yuming
    Li, Xiaoyan
    Park, Kyusung
    Lu, Wei
    Wang, Chao
    Xue, Weijiang
    Yang, Fei
    Zhou, Jiang
    Suo, Liumin
    Lin, Tianquan
    Huang, Haitao
    Li, Ju
    Goodenough, John B.
    [J]. CHEM, 2017, 3 (01): : 152 - 163
  • [2] Hollow-tunneled graphitic carbon nanofibers through Ni-diffusion-induced graphitization as high-performance anode materials
    Chen, Yuming
    Li, Xiaoyan
    Zhou, Xiangyang
    Yao, Haimin
    Huang, Haitao
    Mai, Yiu-Wing
    Zhou, Limin
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (08) : 2689 - 2696
  • [3] Separators for Lithium-Ion Batteries: A Review on the Production Processes and Recent Developments
    Deimede, Valadoula
    Elmasides, Costas
    [J]. ENERGY TECHNOLOGY, 2015, 3 (05) : 453 - 468
  • [4] Preparation of nano-structured LiFePO4/graphene composites by co-precipitation method
    Ding, Y.
    Jiang, Y.
    Xu, F.
    Yin, J.
    Ren, H.
    Zhuo, Q.
    Long, Z.
    Zhang, P.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (01) : 10 - 13
  • [5] The ionic conductivity and mechanical property of electrospun P(VdF-HFP)/PMMA membranes for lithium ion batteries
    Ding, Yanhuai
    Zhang, Ping
    Long, Zhilin
    Jiang, Yong
    Xu, Fu
    Di, Wei
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2009, 329 (1-2) : 56 - 59
  • [6] Temperature-dependent on/off PVP@TiO2 separator for safe Li-storage
    Jiang, Yunhong
    Ding, Yanhuai
    Zhang, Ping
    Li, Feng
    Yang, Zhongmei
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2018, 565 : 33 - 41
  • [7] Thermal degradation characteristics of rigid polyurethane foam and the volatile products analysis with TG-FTIR-MS
    Jiao, Lingling
    Xiao, Huahua
    Wang, Qingsong
    Sun, Jinhua
    [J]. POLYMER DEGRADATION AND STABILITY, 2013, 98 (12) : 2687 - 2696
  • [8] A review of recent developments in membrane separators for rechargeable lithium-ion batteries
    Lee, Hun
    Yanilmaz, Meltem
    Toprakci, Ozan
    Fu, Kun
    Zhang, Xiangwu
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (12) : 3857 - 3886
  • [9] Preparation and properties of poly(ethylene oxide) gel filled polypropylene separators and their corresponding gel polymer electrolytes for Li-ion batteries
    Li, Hao
    Ma, Xiao-Ting
    Shi, Jun-Li
    Yao, Zhi-Kan
    Zhu, Bao-Ku
    Zhu, Li-Ping
    [J]. ELECTROCHIMICA ACTA, 2011, 56 (06) : 2641 - 2647
  • [10] Exceptional electrochemical performance of porous TiO2-carbon nanofibers for lithium ion battery anodes
    Li, Xiaoyan
    Chen, Yuming
    Zhou, Limin
    Mai, Yiu-Wing
    Huang, Haitao
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (11) : 3875 - 3880