Assembly of porous lanthanide metal-organic frameworks constructed by chalcone dicarboxylic acid and exploration of their properties

被引：20

作者：

Pan, Wei ^{[1
,2
,4
]}

Gong, Chunhua ^{[2
,4
]}

Zeng, Xianghua ^{[2
,4
]}

Hu, Chenyan ^{[2
]}

Zhang, Yi ^{[2
]}

Zhu, Dun-Ru ^{[1
]}

Xu, Hao ^{[2
]}

Guo, Haiyang ^{[2
]}

Zhang, Junyong ^{[2
,4
]}

Xie, Jingli ^{[2
,3
,4
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, Nanjing 211816, Jiangsu, Peoples R China

[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China

[3] GTIIT, Guangdong Prov Lab Chem & Fine Chem Engn Shantou, 241 Daxue Rd, Shantou 515063, Guangdong, Peoples R China

[4] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

POLYHEDRON | 2019年 / 169卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic frameworks; Lanthanide; Solvothermal; Porosity; Dye degradation; COORDINATION POLYMERS; LN-MOF; LUMINESCENT; PHOTOLUMINESCENCE; DEGRADATION; CATALYSTS; REMOVAL; SENSOR;

D O I：

10.1016/j.poly.2019.04.062

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using rational designed chalcone dicarboxylic acid ligand (H2L), a series of lanthanide metal-organic frameworks (Ln-MOFs) with the general formula Ln(HL)(3) (Ln = La; Ce; Pr; Nd; Sm; Eu; Gd) have been obtained under the solvothermal reaction. The crystal structure analysis displays that all the Ln-MOFs are the isomorphic three-dimensional (3D) metal-organic frameworks with honeycomb cavities, in which the porosity is similar to 20% that calculated via PLATON software. In addition, photocatalytic activities of Ln-MOFs for the degradation of several organic dyes have been explored, suggesting that Ln-MOFs can be used as efficient heterogeneous photocatalyst for the degradation of organic dyes. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：24 / 31

页数：8

共 50 条

[41] The Road to Functional Lanthanide-Phosphonate Metal-Organic Frameworks [J].

Paz, F. Almeida .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2014, 70 :C1228-C1228

[42] Synthesis, Crystal Structures and Properties of Two Metal-Organic Frameworks Constructed from Pyridine Dicarboxylate and Flexible Bis(imidazole) Ligand [J].

Zhou, Yong-Hong .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2013, 23 (05) :1189-1194

[43] Metal-organic frameworks based on copper(I) iodide and pyridine-3,5-dicarboxylic acid: Synthesis, crystal structures and luminescent properties [J].

Demir, Selcuk ;

Cepni, Hamide Merve ;

Bilgin, Nuray ;

Holynska, Malgorzata ;

Yilmaz, Fatih .

POLYHEDRON, 2016, 115 :236-241

[44] Porous Interpenetrated Zirconium-Organic Frameworks (PIZOFs): A Chemically Versatile Family of Metal-Organic Frameworks [J].

Schaate, Andreas ;

Roy, Pascal ;

Preusse, Thomas ;

Lohmeier, Sven Jare ;

Godt, Adelheid ;

Behrens, Peter .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (34) :9320-9325

[45] Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties [J].

Zhao Can ;

Zhang You ;

Xie Meng-Lin ;

Wu Meng-Qin ;

Wen Yi-Hang .

CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (04) :781-788

[46] Synthesis, crystal structure and fluorescent properties of two metal-organic frameworks constructed from Cd(II) and 2,6-naphthalene dicarboxylic acid [J].

Gangu, Kranthi Kumar ;

Dadhich, Anima S. ;

Mukkamala, Saratchandra Babu .

INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (03) :313-319

[47] Decoding the Mechanistic Strategies of Lanthanide-based Luminescent Metal-Organic Frameworks towards Antibiotic Detection [J].

Yazhini, Crescentia ;

Mathew, Georgeena ;

Anpo, Masakazu ;

Maurin, Guillaume ;

Choi, Wonyong ;

Neppolian, Bernaurdshaw .

ADVANCED OPTICAL MATERIALS, 2024, 12 (01)

[48] Metal-organic frameworks: a new class of porous materials [J].

Rowsell, JLC ;

Yaghi, OM .

MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (1-2) :3-14

[49] Metal-Organic Frameworks Constructed from D-Camphor Acid: Bifunctional Properties Related to Luminescence Sensing and Liquid-Phase Separation [J].

Wen, Lili ;

Xu, Xiaoyue ;

Lv, Kangle ;

Huang, Yumei ;

Zheng, Xiaofang ;

Zhou, Li ;

Sun, Renqiang ;

Li, Dongfeng .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (07) :4449-4455

[50] Synthesis, Structures and Luminescence Properties of Metal-Organic Frameworks Based on Lithium-Lanthanide and Terephthalate [J].

Abdelbaky, Mohammed S. M. ;

Amghouz, Zakariae ;

Garcia-Granda, Santiago ;

Garcia, Jose R. .

POLYMERS, 2016, 8 (03)

← 1 2 3 4 5 →