KOH activation of needle coke to develop activated carbons for high-performance EDLC

被引:136
作者
Qiao, Wenming
Yoon, Seong-Ho
Mochida, Isao
机构
[1] E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
[2] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
关键词
D O I
10.1021/ef050313l
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Petroleum- based needle coke was activated by KOH to develop high- performance activated carbons as carbon electrodes for an electric double- layer capacitor ( EDLC). The effect of preparation parameters on the properties of activated carbons was investigated, and their EDLC properties were measured in an organic electrolytic solution. As-prepared activated carbons ( NCD- ACs) exhibit large surface areas ( 400- 2900 m(2)/ g), high EDLC capacitances (14- 44 F/g), and low system resistances (8.3- 18.7 Omega) on the basis of the anisotropic texture of their precursor.
引用
收藏
页码:1680 / 1684
页数:5
相关论文
共 27 条
[1]   Electrode optimisation for carbon power supercapacitors [J].
Bonnefoi, L ;
Simon, P ;
Fauvarque, JF ;
Sarrazin, C ;
Dugast, A .
JOURNAL OF POWER SOURCES, 1999, 79 (01) :37-42
[2]  
Conway B. E., 1999, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, P221, DOI [10.1007/978-1-4757-3058-6_1, DOI 10.1007/978-1-4757-3058-6_10, 10.1007/978-1-4757-3058-6, DOI 10.1007/978-1-4757-3058-6]
[3]   Morphology and organic EDLC applications of chemically activated AR-resin-based carbons [J].
Endo, M ;
Kim, YJ ;
Ohta, H ;
Ishii, K ;
Inoue, T ;
Hayashi, T ;
Nishimura, Y ;
Maeda, T ;
Dresselhaus, MS .
CARBON, 2002, 40 (14) :2613-2626
[4]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[5]   Enhanced capacitance of carbon nanotubes through chemical activation [J].
Frackowiak, E ;
Delpeux, S ;
Jurewicz, K ;
Szostak, K ;
Cazorla-Amoros, D ;
Béguin, F .
CHEMICAL PHYSICS LETTERS, 2002, 361 (1-2) :35-41
[6]   PVDC-based carbon material by chemical activation and its application to nonaqueous EDLC [J].
Kim, YJ ;
Masutzawa, Y ;
Ozaki, S ;
Endo, M ;
Dresselhaus, MS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (06) :E199-E205
[7]   Preparation of spherical activated carbon with high electric double-layer capacitance [J].
Lee, SI ;
Mitani, S ;
Yoon, SH ;
Korai, Y ;
Mochida, I .
CARBON, 2004, 42 (11) :2332-2334
[8]  
Lillo-Ródenas MA, 2001, CARBON, V39, P751, DOI 10.1016/S0008-6223(00)00186-X
[9]   Understanding chemical reactions between carbons and NaOH and KOH -: An insight into the chemical activation mechanism [J].
Lillo-Ródenas, MA ;
Cazorla-Amorós, D ;
Linares-Solano, A .
CARBON, 2003, 41 (02) :267-275
[10]   Properties of electric double-layer capacitors with various polymer gel electrolytes [J].
Liu, XJ ;
Osaka, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :3066-3071