In the present work we discuss the dynamical processes guiding the relaxation of the internal rotational energy of three diatomic ions, the para-H-2(+), the ortho-D-2(+) and the HD+ in collision with He atoms. The state-changing cross sections and rates for these Molecular Hydrogen Ions (MHIs) are obtained from Close Coupling quantum dynamics calculations and the decay times into their respective ground states are computed by further solving the relevant time-evolution equations. The comparison of the results from the three molecules allows us to obtain a detailed understanding, and a deep insight, on the relative efficiencies of the relaxation processes considered.
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UCL, Dept Phys & Astron, London WC1E 6BT, England
Univ Bari, Dipartimento Chim, I-70126 Bari, ItalyUCL, Dept Phys & Astron, London WC1E 6BT, England
Coppola, C. M.
;
Lodi, L.
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UCL, Dept Phys & Astron, London WC1E 6BT, EnglandUCL, Dept Phys & Astron, London WC1E 6BT, England
Lodi, L.
;
Tennyson, J.
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UCL, Dept Phys & Astron, London WC1E 6BT, EnglandUCL, Dept Phys & Astron, London WC1E 6BT, England
机构:
UCL, Dept Phys & Astron, London WC1E 6BT, England
Univ Bari, Dipartimento Chim, I-70126 Bari, ItalyUCL, Dept Phys & Astron, London WC1E 6BT, England
Coppola, C. M.
;
Lodi, L.
论文数: 0引用数: 0
h-index: 0
机构:
UCL, Dept Phys & Astron, London WC1E 6BT, EnglandUCL, Dept Phys & Astron, London WC1E 6BT, England
Lodi, L.
;
Tennyson, J.
论文数: 0引用数: 0
h-index: 0
机构:
UCL, Dept Phys & Astron, London WC1E 6BT, EnglandUCL, Dept Phys & Astron, London WC1E 6BT, England