Homoleptic ruthenium (II) complexes containing asymmetric tridentate 2-(benzimidazole-2-yl)-1,10-phenanthroline likes ligands: syntheses, characterization and DNA binding

被引：4

作者：

Jiang, CW ^{[1
]}

机构：

[1] Guangxi Univ Tradit Chinese Med, Inst Chinese Mat Med, Sch Pharm, Nanning 530001, Guangxi, Peoples R China

来源：

JOURNAL OF INORGANIC BIOCHEMISTRY | 2004年 / 98卷 / 08期

关键词：

ruthenium (II) complexes; asymmetric tridentate ligands; polypyridine ligands; DNA binding;

D O I：

10.1016/j.jinorgbio.2004.04.013

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Two novel homoleptic ruthenium (11) complexes containing asymmetric tridentate ligands, 2-(benzimidazole-2-yl)-1,10-phenanthroline (PHBI) and 2-(naphtho[2,3-d]imidazole-2-yl)-1,10-phenanthroline (PHNI) have been synthesized and characterized by elemental analysis, mass spectra, H-1 NMR, and electronic spectroscopy. The DNA-binding properties of the complexes have been investigated by spectroscopic methods and viscosity measurements. The results indicate that the two complexes interact with DNA via electrostatic interaction, and the mechanisms of DNA binding with the complexes have also been discussed. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：1399 / 1404

页数：6

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