Removal of Cu2+ and turbidity from wastewater by mercaptoacetyl chitosan

被引:71
作者
Chang, Qing [1 ]
Zhang, Min [1 ]
Wang, Jinxi [1 ]
机构
[1] Lanzhou Jiaotong Univ, Sch Environm & Municipal Engn, Lanzhou 730070, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
Flocculation; Mercaptoacetyl chitosan; Copper; Chitosan; Mercaptoacetic acid; PROTEINS;
D O I
10.1016/j.jhazmat.2009.03.144
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A macromolecule heavy metal flocculant mercaptoacetyl chitosan (MAC) was prepared by reacting chitosan with mercaptoacetic acid. In preliminary experiments, the flocculation performance of MAC was evaluated by using wastewater containing Cu2+ or/and turbidity. Some factors which affect the removal of Cu2+ and turbidity were also studied. The experimental results showed that: (1) MAC can remove both Cu2+ and turbidity from wastewater. The removal efficiency of Cu2+ by using MAC combined with hydrolyzed polyacrylamide is higher than that by only using MAC, the removal efficiency of Cu2+ reaches above 98%; (2) when water sample containing not only Cu2+ but also turbidity-causing substance, the removal efficiency of both Cu2+ and turbidity will be promoted by the cooperation effect of each other, the residual concentration of Cu2+ reaches below 0.5 mgL(-1) and the turbidity reaches below 3 NTU, Cu2+ is more easily removed by MAC when turbidity is higher: (3) the removal efficiency of Cu2+ increases with the increase in pH value, contrarily removal efficiency of turbidity decreases with the increase in pH value. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:621 / 625
页数:5
相关论文
共 14 条
  • [1] COPPER(II) INTERACTION AND COMPLEXATION WITH 1-[2(S)-3-MERCAPTO-3-METHYLPROPIONYL]-L-PROLINE (CAPTOPRIL)
    BONTCHEV, PR
    GOCHEV, G
    EVTIMOVA, B
    KADUM, H
    NACHEV, C
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 1992, 46 (01) : 23 - 34
  • [2] Chang Q., 2003, FLOCCULATION WATER T, P164
  • [3] [常青 CHANG Qing], 2006, [环境化学, Environmental Chemistry], V25, P176
  • [4] Chaudhari S, 1999, J APPL POLYM SCI, V71, P1325, DOI 10.1002/(SICI)1097-4628(19990222)71:8<1325::AID-APP12>3.0.CO
  • [5] 2-F
  • [6] *CHIN ENV AG, 2002, MON METH WAT WAST, P351
  • [7] BIOLOGICAL ANALOGS - SPECTROSCOPIC CHARACTERISTICS OF MERACAPTO-COPPER(II) AND DISULFIDE-COPPER(II) COORDINATION IN RELATION TO TYPE-I PROTEINS
    DOWNES, JM
    WHELAN, J
    BOSNICH, B
    [J]. INORGANIC CHEMISTRY, 1981, 20 (04) : 1081 - 1086
  • [8] HUANG L, 1998, ADSORPTION BINDING B, P115
  • [9] Catalytic behavior of 3-mercapto-1-propane sulfonic acid on Cu electrodeposition and its effect on Cu film properties for CMOS device metallization
    Kim, JJ
    Kim, SK
    Kim, YS
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 542 : 61 - 66
  • [10] RONALD RN, 2003, SEP SCI TECHNOL, V38, P2327