Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene -: VI:: Application of observed trends to stannyl derivatives

被引：2

作者：

Panchenko, YN

De Maré, GR

Abramenkov, AV

Baird, MS

Tverezovsky, VV

Nizovtsev, AV

Bolesov, IG

机构：

[1] Free Univ Brussels, Fac Sci, Serv Chim Quant & Photophys Atomes Mol & Atmosphe, B-1050 Brussels, Belgium

[2] Moscow MV Lomonosov State Univ, Dept Chem, Div Phys Chem, Lab Mol Spect, Moscow 119899, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Div Phys Chem, Lab Mol Struct & Quantum Mech, Moscow 119899, Russia

[4] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

[5] Moscow MV Lomonosov State Univ, Dept Chem, Div Organ Chem, Lab Organoelement Cpds, Moscow 119899, Russia

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2004年 / 60卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

3,3-dimethyl-1,2-bis(tert-butyl)cyclopropene; 3,3-dimethyl-1,2-bis(trimethylsilyl)cyclopropene; 3,3-dimethyl-1,2-bis(trimethylgermyl)cyclopropene; 3,3-dimethyl-1-(trimethylsilyl)cyclopropene; 3,3-dimethyl-1-(trimethylgermyl)cyclopropene; 3,3-dimethyl-1,2-bis(trimethylstannyl)cyclopropene; 3,3-dimethyl-1-(trimethylstannyl)cyclopropene; vibrational spectra; regularities;

D O I：

10.1016/j.saa.2003.12.044

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The effects of substitution of X = C by Si or Ge in X(CH3)(3) moieties attached to the formal double bond of 3,3-dimethylcyclopropene are examined. Regularities in observed trends of vibrational frequencies implicating the moieties containing the X atom, as the X atomic mass is increased, are extrapolated to X = Sn. The results of this extrapolation made it possible to assign the known experimental vibrational frequencies of 3,3-dimethyl-1-(trimethylstannyl)cyclopropene and 3,3-dimethyl-1,2-bis(trimethylstannyl)cyclopropene. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：2511 / 2516

页数：6

共 12 条

[1] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene -: III.: 3,3-dimethyl-1-(trimethylsilyl)cyclopropene
De Maré, GR
Panchenko, YN
Abramenkov, AV
Baird, MS
Tverezovsky, VV
Nizovtsev, AV
Bolesov, IG
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (09) : 2063 - 2072
[2] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, trimethylgermyl, trimethylstannyl, and trimethylplumbyl derivatives of 3,3-dimethylcyclopropene X.: Some regularities
Panchenko, Yu. N.
De Mare, G. R.
Pupyshev, V. I.
Abramenkov, A. V.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 68 (05) : 1334 - 1339
[3] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, trimethylgermyl, trimethylstannyl and trimethylplumbyl derivatives of 3,3-dimethylcyclopropene. XII. 1,2-Di-tert-butyl-3,3-dimethylcyclopropene
de Meijere, Armin
Sokolov, Viktor V.
Yufit, Dmitry S.
Panchenko, Yurii N.
De Mare, George R.
Abramenkov, Alexander V.
Lokshin, Boris V.
Senyavin, Vladimir M.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 75 (04) : 1253 - 1260
[4] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene IV.: 3,3-dimethyl-1,2-bis(trimethylgermyl)cyclopropene
Panchenko, YN
De Maré, GR
Abramenkov, AV
Baird, MS
Tverezovsky, VV
Nizovtsev, AV
Bolesov, IG
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (08) : 1733 - 1744
[5] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, trimethylgermyl, and trimethylstannyl derivatives of 3,3-dimethylcyclopropene -: VII.: 3,3-dimetliyl-1-(trimethylstannyl) cyclopropene
Panchenko, Yu. N.
De Mare, G. R.
Abramenkov, A. V.
de Meijere, A.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 65 (02) : 351 - 357
[6] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene -: II.: 3,3-dimethyl-1,2-bis(trimelthylsilyl)cyclopropene
Panchenko, YN
De Maré, GR
Abramenkov, A
Baird, MS
Tverezovsky, VV
Nizovtsev, A
Bolesov, IG
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (09) : 2087 - 2098
[7] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, trimethylgermyl, trimethylstannyl and trimethylplumbyl derivatives of 3,3-dimethylcyclopropene. XI. Secondary periodicity
Panchenko, Yurii N.
Abramenkov, Alexander V.
De Mare, George R.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 73 (04) : 782 - 786
[8] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene.: I.: 3,3-dimethyl-1,2-bis(tert-butyl)cyclopropene
Panchenko, YN
De Maré, GR
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (02) : 329 - 334
[9] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, trimethylgerml, trimethlstannyl, and trimethylplumbyl derivatives of 3,3-dimethylcyclopropene -: IX.: 3,3-Dimethyl-1-(trimethylplumbyl)cyclopropene
De Mare, G. R.
Panchenko, Yu. N.
Abramenkov, A. V.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 67 (3-4) : 1094 - 1100
[10] Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethyl cyclopropene -: V.: 3,3-Dimethyl-1-(trimethylgermyl)cyclopropene
De Maré, GR
Panchenko, YN
Abramenkov, AV
Baird, MS
Tverezovsky, VV
Nizovtsev, AV
Bolesov, IG
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (03) : 519 - 526

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