Gas-phase ionic reactions of benzyl and methoxide anions

被引:0
|
作者
Gatev, GG [1 ]
Zhong, ML [1 ]
Brauman, JI [1 ]
机构
[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
关键词
gas-phase ionic reactions; benzyl anions; methoxide anions;
D O I
10.1002/(SICI)1099-1395(199707)10:7<531::AID-POC911>3.3.CO;2-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Gas-phase reactions of benzyl and methoxide anions with alkyl formate and other esters were compared using Fourier transform io cyclotron resonance spectroscopy. Although these anions have similar basicities, in many cases the reaction pathways differ. (C) 1997 by John Wiley & Sons, Ltd.
引用
收藏
页码:531 / 536
页数:6
相关论文
共 50 条
  • [21] GAS-PHASE IONIC REACTIONS ARE GENERALLY STEPWISE PROCESSES
    MCADOO, DJ
    HUDSON, CE
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1984, 62 (03): : 269 - 276
  • [22] ISOMERIZATION-REACTIONS OF BETA-ETHYL ANIONS IN THE GAS-PHASE
    DOWNARD, KM
    HAYES, RN
    BOWIE, JH
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (10): : 1815 - 1819
  • [23] REACTIONS OF TRANSITION-METAL CARBONYL ANIONS WITH DIOXYGEN IN THE GAS-PHASE
    LANE, K
    SALLANS, L
    SQUIRES, RR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) : 2719 - 2721
  • [24] GAS-PHASE REACTIONS - IONIZATION BY PROTON-TRANSFER TO SUPEROXIDE ANIONS
    DZIDIC, I
    CARROLL, DI
    STILLWEL.RN
    HORNING, EC
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (16) : 5258 - 5259
  • [25] GAS-PHASE PROTON-TRANSFER REACTIONS BETWEEN ALKOXIDE ANIONS
    DODD, JA
    BAER, S
    MOYLAN, CR
    BRAUMAN, JI
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) : 5942 - 5949
  • [26] Gas-Phase Reactions of Chlorine Oxide Anions with Ozone: Atmospheric Implications
    Brydon, Samuel C.
    Poad, Berwyck L. J.
    Marshall, David L.
    Fourie, Waldo C.
    Kelly, Patricia D.
    Ucur, Boris
    Bieske, Evan J.
    Trevitt, Adam J.
    Blanksby, Stephen J.
    ACS EARTH AND SPACE CHEMISTRY, 2025,
  • [27] Recent advances in the energetics and mechanisms of gas-phase ionic reactions
    Riveros, JM
    Sena, M
    Guedes, GH
    Xavier, LA
    Slepetys, R
    PURE AND APPLIED CHEMISTRY, 1998, 70 (10) : 1969 - 1976
  • [28] BIOMOLECULAR IONIC ALKENE DISPLACEMENT-REACTIONS IN THE GAS-PHASE
    AUDIER, HE
    MOURGUES, P
    LEBLANC, D
    HAMMERUM, S
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1993, 317 (01): : 27 - 31
  • [29] RECENT RADIOLYTIC STUDIES ON THE MECHANISM OF GAS-PHASE IONIC REACTIONS
    CACACE, F
    RADIATION PHYSICS AND CHEMISTRY, 1982, 20 (01): : 99 - 110
  • [30] Gas-phase ionic reactions: Dynamics and mechanism of nucleophilic displacements
    Chabinyc, ML
    Craig, SL
    Regan, CK
    Brauman, JI
    SCIENCE, 1998, 279 (5358) : 1882 - 1886